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Dissolution of K-feldspar into Si-Al gel and crystallization of halloysite identified in the kaolin deposit of Sao Vicente de Pereira (Portugal)

Title
Dissolution of K-feldspar into Si-Al gel and crystallization of halloysite identified in the kaolin deposit of Sao Vicente de Pereira (Portugal)
Type
Article in International Scientific Journal
Year
2000
Authors
Bobos, I
(Author)
Other
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Gomes, C
(Author)
Other
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Journal
Title: Geologica CarpathicaImported from Authenticus Search for Journal Publications
Vol. 51
Pages: 49-57
ISSN: 1335-0552
Scientific classification
FOS: Natural sciences > Earth and related Environmental sciences
Other information
Authenticus ID: P-001-0WY
Abstract (EN): Dissolution of K-feldspar into Si-Al non-crystalline phase was identified in the kaolin deposit of Sao Vicente de Pereira (Portugal). The gel having a SiO2/Al2O3 ratio approximately equal to the unity, crystallized into halloysite-0.7 nm. SEM investigations carried out on K-feldspar grains show a vacuolar texture characterized by etch-pits of various dimensions. The pits exhibit various shapes, either polygonal or circular. The gel was identified by SEM on the K-feldspar surfaces and by TEM in the < 2 mu m clay fractions. TEM images display tubes of halloysite-0.7 nm surrounding flakes of SI-AI gel. Relicts of K-feldspar pseudomorphs submitted to amorphization are identified by TEM. SAED analyses confirmed the non-crystalline state of the gel. Electron microprobe analyses attested a very fast destabilization of the chemical structure of K-feldspar grains.
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 9
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