Abstract (EN):
The recently reported compound (+)-(1 R,endo)-2-benzonorbornenol (2) proved to be an efficient chiral auxiliary in the asymmetric aza-Diels-Alder reaction between cyclopentadiene and the N-benzyl imine of its glyoxylate, which afforded a virtually all-exo mixture of cycloaducts with a ISAR diastereomeric ratio of 63:37.
Language:
English
Type (Professor's evaluation):
Scientific
Contact:
qoxgmera@usc.es
No. of pages:
3