Integrated design of hematite and dye-sensitized solar cell for unbiased solar charging of an organic-inorganic redox flow battery

• Type: Article in International Scientific Journal
• Date: 2019

Authors

Amirreza Khataee (Author) Other; João Azevedo (Author) FEUP; Paula Dias (Author) FEUP; Dzmitry Ivanou (Author) FEUP; Emil Dra¸ević (Author) Other; Anders Bentien (Author) Other; Adélio Mendes (Author) FEUP

Journal

Title: Nano Energy

Vol. 62

Pages: 832-843

ISSN: 2211-2855

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 0 Citations

ISI Web of Science

Scopus - 17 Citations

INSPEC

Associated Projects

LEPABE - Projeto Estratégico do LEPABE - Laboratório de Engenharia de Processos, Ambiente, Biotecnologia e Energia

LEPABE - Laboratório de Engenharia de Processos, Ambiente, Biotecnologia e Energia

LEPABE-2-ECO-INNOVATION - LEPABE-2-ECO-INNOVATION

HopeH2 - Dispositivo tandem PEC-PV eficiente, estável e escalável para geração de hidrogénio solar

SunStorage - Recolha e armazenamento de energia solar

SunFlow - Armazenamento de energia solar em baterias redox de caudal

Other information

Authenticus ID: P-00Q-QFH

DOI: 10.1016/j.nanoen.2019.06.001

Abstract (EN): Integration of the photoelectrochemical cells and redox flow batteries (RFBs) is conceptualized as solar redox flow cells (SRFCs). The SRFC opens an opportunity for simultaneous electrochemical conversion and storage of solar energy in a single device. This work proposes a SRFC which integrates stable hematite (alpha-Fe2O3) photoanode with a near-neutral organic-inorganic RFB using organic and low-cost redox pair anthraquinone-2,7-disulfonate disodium (AQDS) on the negative side and iodide/iodine (I-/I-2) redox couple on the positive side. The AQDS/iodide RFB exhibited a stable battery cycling with a cell voltage of similar to 0.8 V, a high coulombic efficiency of 99.2% and a peak power density of 0.22 W.cm(-2). The hematite yielded a stable performance in contact with iodide/iodine solution with pH 5.5, despite known stability issues for pH < 7. Electrochemical impedance spectroscopy was used to elucidate the main semiconductor/electrolyte charge transfer mechanisms and rates and energy level alignment of hematite with redox pair voltages. Finally, to photocharge the AQDS/iodide SRFC unbiasedly, a tandem system was used which includes hematite photoelectrode connected in series with a dye-sensitized solar cell (DSSC). The tandem photoelectrode provided 1.6 V of photovoltage that is sufficient to fully charge the RFB.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 12