Spectral sensitization of TiO2 with electrodeposited PbSe: improvement of photocurrent stability and light conversion efficiency

• Type: Article in International Scientific Journal
• Date: 2017-08-08

Authors

Dzmitry Ivanou (Author) FEUP; Yu. A. Ivanova (Author) Other; S.K. Poznyak (Author) Other; M. Starykevich (Author) Other; M. Ferreira (Author) Other; Adélio Mendes (Author) FEUP; E.A. Streltsov (Author) Other

Journal

Title: Electrochimica Acta

Vol. 249

Pages: 369-376

ISSN: 0013-4686

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 3 Citations

ISI Web of Science

Scopus - 4 Citations

Associated Projects

BI-DSC - Building Integrated Dye Sensitized Solar Cells

LEPABE-2-ECO-INNOVATION - LEPABE-2-ECO-INNOVATION

Other information

Authenticus ID: P-00M-XP1

DOI: 10.1016/j.electacta.2017.08.018

Abstract (EN): This work focuses on spectral sensitization of mesoporous TiO2 films and Nb-doped TiO2 films with polydisperse PbSe nanoparticles (TiO2/PbSe). For this, PbSe was electrochemically deposited from aqueous solution containing Pb2+ cations and SeO2. Chemical amount of electrodeposited PbSe was controlled by deposition time and impacted on the magnitude of sensitized photocurrents. The efficacy of different ions (S-n(2-); I-3(-); H2PO4-; N2H5+; SO32-; SCN-, SeSO32-) as hole scavengers for TiO2/PbSe photoanodes was assessed by dynamics of photocurrent in polarization measurements. Electrolyte of Na2SO3 and Na2SeSO3 is reported as an effective one to attain stable photocurrent. Photoelectrochemical cells with TiO2/PbSe photoanodes show solar to electricity conversion efficiency of 0.09%, in spectral region up to 700 nm for undoped TiO2. Enhancement of the photoresponse was achieved by different level of Nb doping into mesoporous TiO2 film. Extension of spectral response up to 800 nm and photocurrent conversion efficiency of 0.24% is observed for TiO2/PbSe photoanodes with 2.5 at% Nb-doped TiO2. Doping with Nb results in positive shift on electrochemical scale of conduction band of TiO2. It favors the collection of photoelectrons from PbSe nanoparticles that have light absorption in wider spectral region.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 8