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Simultaneous catalytic conversion of cellulose and corncob xylan under temperature programming for enhanced sorbitol and xylitol production

Title
Simultaneous catalytic conversion of cellulose and corncob xylan under temperature programming for enhanced sorbitol and xylitol production
Type
Article in International Scientific Journal
Year
2017
Authors
José Melo Orfão
(Author)
FEUP
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Manuel Fernando R Pereira
(Author)
FEUP
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Journal
Vol. 244
Pages: 1173-1177
ISSN: 0960-8524
Publisher: Elsevier
Other information
Authenticus ID: P-00N-0A9
Abstract (EN): Sorbitol and xylitol yields can be improved by converting cellulose and xylan simultaneously, due to a synergetic effect between both substrates. Furthermore, both yields can be greatly enhanced by simply adjusting the reaction conditions regarding the optimum for the production of each product, since xylitol (from xylan) and sorbitol (from cellulose) yields are maximized when the reaction is carried out at 170 and 205 degrees C, respectively. Therefore, the combination of a simultaneous conversion of cellulose and xylan with a two-step temperature approach, which consists in the variation of the reaction temperature from 170 to 205 degrees C after 2 h, showed to be a good strategy for maximizing the production of sorbitol and xylitol directly from mixture of cellulose and xylan. Using this new and environmentally friendly approach, yields of sorbitol and xylitol of 75 and 77%, respectively, were obtained after 6 h of reaction.
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 5
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