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A nickel complex with an asymmetric N2OS Schiff base ligand

Title
A nickel complex with an asymmetric N2OS Schiff base ligand
Type
Article in International Scientific Journal
Year
1997
Authors
deCastro, B
(Author)
FCUP
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Pereira, E
(Author)
FCUP
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Gomes, L
(Author)
Other
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Journal
Vol. 53
Pages: 1572-1574
ISSN: 0108-2701
Publisher: Blackwell
Scientific classification
FOS: Natural sciences > Chemical sciences
Other information
Authenticus ID: P-001-AA6
Abstract (EN): In the structure of the title complex, {methyl 2-{2-[(2-hydroxyphenyl)methyleneamino]ethylamino}-1-cyclopentenedithiocarboxylato-O,N,N',S}nickel(II), [Ni(C16H18N2OS2)], the Ni-II atom is coordinated by S, O and two N atoms in a nearly planar environment. The two inequivalent N atoms, coordinated in a cis manner, show virtually identical bond lengths and angles indicating that the NS ligand fragment coordinates as a Schiff base ligand, with the N atom behaving as an imine and the S atom having a strong thiolate character.
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 3
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