Effect of relative humidity during the preparation of perovskite solar cells: Performance and stability

• Tipo: Artigo em Revista Científica Internacional
• Data: 2020-03

Autores

Mesquita, I. (Autor) FEUP; Andrade, L. (Autor) FEUP; Adélio Mendes (Autor) FEUP

Revista

Título: Solar Energy

Vol. 199

Páginas: 474-483

ISSN: 0038-092X

Editora: Elsevier

Indexação

ISI Web of Knowledge - 3 Citações

Scopus - 10 Citações

BASE - Bielefeld Academic Search Engine

ScienceDirect (Elsevier)

Classificação Científica

FOS: Ciências da engenharia e tecnologias > Engenharia química

Projetos Associados

LEPABE-2-ECO-INNOVATION - LEPABE-2-ECO-INNOVATION

LEPABE - Financiamento Plurianual 2020-2023 da Unidade de I&D LEPABE - Laboratório de Engenharia de Processos, Ambiente, Biotecnologia e Energia

Outras Informações

ID Authenticus: P-00R-RKY

DOI: 10.1016/j.solener.2020.02.052

Abstract (EN): Humidity is one of the main environmental factors that limits performance and stability of perovskite solar cells (PSC); it plays a critical role during the preparation of the perovskite film, influencing the crystal growth. In this work, it is investigated the effect of the relative humidity (RH) and type of atmosphere (nitrogen vs air) used during the deposition of both perovskite layer and hole extraction layer (HEL). While humidity and oxygen seem not to affect the HEL deposition step, the perovskite layer is notoriously influenced by the RH and by the presence of oxygen during its deposition. Until 10% of RH, the performance of devices prepared with a triplecation perovskite layer deposited under a nitrogen environment was mostly unaffected, whilst for devices deposited in air that limit is lower. On the other hand, for high RH values (above 30%), devices prepared with a triple-cation perovskite layer deposited under N-2 presented slightly better stability over time than the ones prepared under air. The best-performing device was prepared with a triple-cation perovskite layer deposited under dry air, presenting a power conversion efficiency of 16.7%. These results are of critical value when designing a plant for fabricating PSC showing that the perovskite layer may be deposited under a simple dry air atmosphere (RH < 1%).

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 10