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Pd-catalysed amination on a soluble polymer support: arylation of anilines with PEG-supported aryl halides

Title
Pd-catalysed amination on a soluble polymer support: arylation of anilines with PEG-supported aryl halides
Type
Article in International Scientific Journal
Year
2013
Authors
Luisa C R Carvalho
(Author)
Other
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Marina J D Dias Pires
(Author)
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Eduarda Fernandes
(Author)
FFUP
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Manuel M B Marques
(Author)
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Journal
Title: RSC AdvancesImported from Authenticus Search for Journal Publications
Vol. 3
Pages: 25711-25715
ISSN: 2046-2069
Scientific classification
FOS: Natural sciences > Chemical sciences
Other information
Authenticus ID: P-008-H2D
Abstract (EN): PEG supported aryl halides were found to serve as substrates for the Pd-catalysed N-arylation of several substituted anilines and alkyl amines under solventless conditions. Moreover, the Pd(2)dba(3)/XPhos catalyst system enabled the coupling reactions to take place smoothly with excellent yields under a low catalyst loading (1 mol% Pd and 3 mol% ligand).
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 5
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