Microwave-assisted headspace solid-phase microextraction to quantify polycyclic aromatic hydrocarbons in pine trees

• Type: Article in International Scientific Journal
• Date: 2012

Authors

Nuno Ratola (Author) FEUP; Paulo Herbert (Author) Other; Arminda Alves (Author) FEUP

Journal

Title: Analytical and Bioanalytical Chemistry

Serial No. 6 Vol. 403

Pages: 1761-1769

ISSN: 1618-2642

Publisher: Springer Nature

Indexing

ISI Web of Knowledge - 7 Citations

ISI Web of Science

Scopus - 11 Citations

Scientific classification

FOS: Natural sciences > Chemical sciences

Associated Projects

SAFEPINE - SAFEPINE - Avaliação da contaminação de pinheiros por poluentes emergentes

Other information

Authenticus ID: P-002-9PE

DOI: 10.1007/s00216-012-5962-2

Abstract (EN): A methodology for the extraction and quantification of 16 polycyclic aromatic hydrocarbons (PAHs) based on microwave-assisted extraction coupled with headspace solid-phase microextraction followed by gas chromatography/mass spectroscopy was validated for needles and bark of two pine species ( Ait. and L.). The limits of detection were below 0.92 ng g(-1) (dry weight) for needles and below 0.43 ng g(-1) (dw) for bark. Recovery assays were performed with two sample masses spiked at three levels and the overall mean values were between 70 and 110 % for and 75 and 129 % for . In the first species, the increase in sample mass lowered the recoveries slightly for most PAHs, whereas for the second, the recoveries were higher for the needles. Naturally contaminated samples from 4 sites were analysed, with higher levels for urban sites (1,320 and 942 ng g(-1) (dw) vs. 272 and 111 ng g(-1) (dw) for needles and 696 and 488 ng g(-1) (dw) vs. 270 and 103 ng g(-1) (dw) for bark) than for rural ones and also for samples over . It is also shown that gas-phase PAHs are predominant in the needles (over 65 % of the total PAHs) and that the incidence for particulate material in bark, reaching 40 % as opposed to a maximum below 20 % for the needles. The method has proved to be fit and improved some of the existing approaches, on the assessment of particulate PAHs and bark levels.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 9