Equilibrium Swelling of Polystyrene by Alkanes and Carboxylic Acids: A Simple Quantitative Correlation Model

• Type: Article in International Scientific Journal
• Date: 2010

Authors

Bernardo, G (Author) Other; Vesely, D (Author) Other

Journal

Title: Journal of Applied Polymer Science

Vol. 116

Pages: 1348-1356

ISSN: 0021-8995

Publisher: Wiley-Blackwell

Indexing

ISI Web of Knowledge - 1 Citation

Scopus - 1 Citation

Other information

Authenticus ID: P-003-6SC

DOI: 10.1002/app.31582

Abstract (EN): In this study, we show that the equilibrium saturation swelling of polystyrene by linear alkanes and linear carboxylic acids, as reported earlier (Bernardo and Vesely, Eur Polym J 2007, 43, 4983, Bernardo and Vesely, J Appl Polym Sci 2008, 110, 2393) can be correlated quantitatively using a model where only the alkyl-chain lengths and the saturated vapor pressures of the organic liquids are considered. According to this model, at very low vapor pressures, the number of polystyrene monomer units per solvent molecule is directly proportional to the alkyl chain length of the solvent molecule under consideration. At higher vapor pressures, the number of polystyrene monomer units per solvent molecule tends to become independent of its alkyl chain length. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 116: 1348-1356, 2010

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 9