Photoelectrochromic devices: Influence of device architecture and electrolyte composition

• Type: Article in International Scientific Journal
• Date: 2016

Authors

Cláudia Costa (Author) FEUP; Isabel Mesquita (Author) Other; Luísa Andrade (Author) FEUP; Adélio Mendes (Author) FEUP

Journal

Title: Electrochimica Acta

Vol. 219

Pages: 99-106

ISSN: 0013-4686

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 5 Citations

ISI Web of Science

Scopus - 12 Citations

Scientific classification

CORDIS: Physical sciences > Chemistry > Solar chemistry

Associated Projects

BI-DSC - Building Integrated Dye Sensitized Solar Cells

LEPABE - Laboratório de Engenharia de Processos, Ambiente, Biotecnologia e Energia

Other information

Authenticus ID: P-00M-3SV

DOI: 10.1016/j.electacta.2016.09.142

Abstract (EN): Solar energy harvesting and chromogenic technologies can be integrated together to give self-powered and wireless photoelectrochromic devices (PECD). Due to the similarity in the architecture of both dyesensitized solar cells (DSC) and electrochromic devices (ECD), it is possible to merge these two devices into one combined solar-powered electrochromic device known as DSC-EC. The present work describes the preparation and characterization of electrochromic solar cells using PEDOT:PSS (poly(3,4- ethylenedioxythiophene) polystyrene sulfonate) as electrochromic material in the counter-electrode. Different configurations and liquid and polymer-based electrolytes are studied. The resulting electrochromic solar cells were characterized focusing on the determination of solar to electricity conversion efficiency and the color contrast was assessed using color coordinates under simulated solar irradiation. The best DSC-EC configuration originates a color contrast of (DE = 30) at a potential difference of 0.4 V and energy conversion efficiency of 4.9% at VOC of 0.66 V and JSC of 11 mAcm
2 , when using the liquid electrolyte. On the other hand, the best performing DSC-EC using the polymer-based electrolyte showed a very good color contrast of (DE = 47) at short circuit and an energy conversion efficiency of 1% at VOC of 0.63V and JSC of 4.5 mAcm-2.

Language: English

Type (Professor's evaluation): Scientific

Notes: Journal Citation Reports

No. of pages: 8