Unlocking the power of amorphous TiO₂-decorated biocarbon composite: Enhanced photocatalytic performance for crystal violet dye degradation

• Tipo: Artigo em Revista Científica Internacional
• Data: 2025

Autores

Brandao, ATSC (Autor) Outra; Rosoiu State, S (Autor) Outra; Costa, R (Autor) FCUP; Enache, LB (Autor) Outra; Mihai, GV (Autor) Outra; Vazquez, JA (Autor) Outra; Valcarcel, J (Autor) Outra; Anicai, L (Autor) Outra; Enachescu, M (Autor) Outra; Carlos M Pereira (Autor) FCUP

Revista

Título: Journal of Water Process Engineering

Vol. 71

ISSN: 2214-7144

Editora: Elsevier

Indexação

ISI Web of Knowledge - 3 Citações

Scopus - 4 Citações

Outras Informações

ID Authenticus: P-018-8NR

DOI: 10.1016/j.jwpe.2025.107288

Abstract (EN): This study presents a comprehensive investigation of the morphological and photocatalytic properties of electrochemically synthesized titanium dioxide (TiO2), both in its amorphous (non-calcined) and crystalline (calcinated) forms and its composite with biomass-derived carbon (TiO2@C). The TiO2 materials were synthesized using a deep eutectic solvent (DES)-based electrochemical method, and their properties were compared with commercial TiO2 nano-powder (TiO2_NP). Characterization techniques such as BET, SEM/EDX, XRD, Raman, ATR-FTIR, and XPS were employed to elucidate the structural, textural, and surface chemical properties of the materials. The amorphous TiO2 (TiO2@DES) exhibited significantly higher surface area and pore volume compared to commercial TiO2, while the calcined TiO2 (TiO2@DES_400) displayed enhanced crystallinity with an anatase structure. The TiO2@C composite was prepared via an in-situ decoration of biomass-derived carbon during the TiO2 electrochemical synthesis. This resulted in a material with a high specific surface area (2214 m(2) g(-1)) and porous structure. This composite demonstrated superior photocatalytic performance for the degradation of crystal violet dye under both UV and visible light irradiation, achieving degradation efficiencies of similar to 98 % after 5 h. The TiO2@C composite was further applied to degrade wastewater from leather dye processing, demonstrating its efficacy in real-world applications. These results underscore the potential of the TiO2@C composite as a sustainable and high-performance photocatalyst for environmental remediation, particularly in wastewater treatment.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 14