Electrochemical advanced oxidation processes for sanitary landfill leachate remediation: Evaluation of operational variables

• Tipo: Artigo em Revista Científica Internacional
• Data: 2016

Autores

Francisca C. Moreira (Autor) FEUP; J. Soler (Autor) FEUP; Amélia Fonseca (Autor) FEUP; Isabel Saraiva (Autor) FEUP; Rui A. R. Boaventura (Autor) FEUP; Enric Brillas (Autor) FEUP; Vítor J. P. Vilar (Autor) FEUP

Revista

Título: Applied Catalysis B: Environmental

Vol. 182

Páginas: 161-171

ISSN: 0926-3373

Editora: Elsevier

Indexação

ISI Web of Knowledge - 64 Citações

ISI Web of Science

Scopus - 72 Citações

Classificação Científica

FOS: Ciências da engenharia e tecnologias > Engenharia do ambiente

CORDIS: Ciências Tecnológicas > Tecnologia > Tecnologia ambiental

Projetos Associados

AdvancedLFT - Tecnologia de tratamento de lixiviados de aterros sanitários através da integração de processos de oxidação biológica e foto oxidação química, combinando radiação solar natural e artificial

LSRE-LCM - Laboratório de Processos de Separação e Reação - Laboratório de Catálise e Materiais

LSRE/LCM LA - RL1_P3 - Environmental Technologies

Outras Informações

ID Authenticus: P-00G-P4A

DOI: 10.1016/j.apcatb.2015.09.014

Abstract (EN): The effect of various parameters on the performance of electrochemical advanced oxidation processes (EAOPs) like electro-Fenton (EF), photoelectro-Fenton (PEF) and solar PEF (SPEF) was assessed for the treatment of a sanitary landfill leachate previously subjected to biological and coagulation processes. The tested operational variables included: (i) anode material (boron-doped diamond (BDD) and Pt), (ii) initial total dissolved iron concentration (20-80 mg L-1), (iii) pH (2.8-4.0), (iv) initial addition of 1:3 Fe(III)-to-oxalate molar ratio at various pH values (2.8-5.0), (v) temperature (15-40 degrees C) and (vi) radiation source (UVA, UVA-Vis and UVC lamps and natural sunlight). The BDD anode showed high superiority over the Pt one for EF, PEF with UVA light (PEF-UVA) and SPEF processes, thereby advising an important role of the physisorbed hydroxyl radicals ((OH)-O-center dot) at the anode surface on landfill leachate oxidation even under the potent solar radiation. An initial total dissolved iron content of 60 mg L-1 was chosen as the best dose for the PEF-UVA process with the BDD anode (PEF-BDD-UVA). While PEF-BDD-UVA without external addition of oxalic acid yielded the best results at pH 2.8, the initial addition of 1:3 Fe(III)-to-oxalate molar ratio allowed operating at pH 3.5 with even higher efficiency and at pH 4.0 with only slightly lower efficiency. Effluent temperatures from 20 to 40 degrees C led to similar mineralization rates for the PEF-BDD-UVA technique. The use of UVA and UVC lamps and natural sunlight as radiation sources in PEF-BDD and SPEF-BDD systems led to similar mineralization profiles as a function of time. The UVA-Vis lamp induced lower effluent mineralization mainly for longer reaction times.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 11