Abstract (EN):
The present work aimed at developing a novel water-in-oleogel emulsion using a mixture of gamma-oryzanol and phytosterols as gelator. The gelator network was severely affected by the presence of water, with single beta-sitosterol crystals being the main contributors to the self-standing ability of the emulsions. X-ray analyses have shown sharp crystallographic reflections for anhydrous and hemihydrated beta-sitosterol crystals, independently of the gelator concentrations and water-in-oleogel ratios. The samples with higher water content have shown additional reflections that could be traced back to monohydrated beta-sitosterol crystals, but these were not present after 7 days. The rheological analysis has revealed the impact of the emulsion composition on their strength. Foreseeing their use for the co-delivery of bioactive compounds, we added beta-carotene and epigallocatechin gallate to the emulsions. We confirmed their viability toward the incorporation of bioactives in their free-form, constituting a proof of concept for the fortification of lipid-rich foods with both oil and water-soluble bioactive compounds.
Language:
English
Type (Professor's evaluation):
Scientific
No. of pages:
9