Prediction of Near and Supercritical Fatty Acid Ester + Alcohol Systems with the CPA EoS

• Type: Article in International Scientific Journal
• Date: 2010

Authors

Mariana B. Oliveira (Author) FEUP; António José Queimada (Author) FEUP; João A. P. Coutinho (Author) FEUP

Journal

Title: Journal of Supercritical Fluids

Vol. 52 No. 3

Pages: 241-248

ISSN: 0896-8446

Publisher: Elsevier

Indexing

ISI Web of Science

Scopus

Scientific classification

FOS: Engineering and technology > Chemical engineering

Other information

DOI: 10.1016/j.supflu.2010.01.014

Abstract (EN): The use of supercritical alcohols has been proposed as a non-catalytical method to produce biodiesel, overcoming some of the shortcomings related to conventional catalytic methods. In this work, the Cubic-Plus-Association equation of state is used to predict the vapor–liquid equilibria of several alcohol + fatty acid ester and alcohol + glycerol systems, in the temperature range 493–573 K and pressure range 2–12 MPa. The resulting predictions reproduce accurately the experimental data, within their experimental uncertainty. The ability to predict these phase equilibria is of primary importance for designing, operating and optimizing biodiesel production at near or supercritical conditions. The CPA EoS is shown to be a powerful prediction tool for an adequate design of the operations involved in the biodiesel production with near or supercritical alcohols.

Language: English

Type (Professor's evaluation): Scientific