Spontaneous gold decoration of activated carbons

• Type: Article in International Scientific Journal
• Date: 2013

Authors

B. Jarrais (Author) FCUP; A. R. Silva (Author) Other; L. S. Ribeiro (Author) FEUP; E. G. Rodrigues (Author) FEUP; J. J. M. Órfão (Author) FEUP; M. F. R. Pereira (Author) FEUP; J. L. Figueiredo (Author) FEUP; C. Freire (Author) FCUP

Journal

Title: Inorganica Chimica Acta

Vol. 408

Pages: 235-239

ISSN: 0020-1693

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 3 Citations

ISI Web of Science

Scopus - 3 Citations

Scientific classification

FOS: Engineering and technology

CORDIS: Technological sciences > Engineering

Associated Projects

LA 20 - PROJECTO ESTRATÉGICO - LA 20 - 2013-2014

Other information

Authenticus ID: P-006-6CG

DOI: 10.1016/j.ica.2013.07.008

Abstract (EN): A novel mild method for the preparation of gold supported on activated carbons was achieved through direct reduction of Au3+ ions onto the surface of two different types of activated carbons, namely a non-functionalized commercial type and a chemically modified activated carbon. The chemically modified activated carbon was obtained by gas phase oxidation of the latter, in order to introduce surface oxygen groups. Geometrical and amorphous gold and gold clusters were formed at the surface of the two types of carbon supports, through a straightforward redox reaction under mild conditions. We demonstrated the catalytic performance of gold supported on activated carbon in the oxidation of glycerol, which presented high activity and selectivity towards the formation of glyceric acid.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 5