| Summary: |
One of the main concerns of modern society is reducing its dependence on fossil fuels. Due to their low cost and low environmental impact, electrical energy storage devices are
among the most promising alternatives to conventional fossil fuels, as the electricity generated from renewable sources may be efficiently stored. In particular, lithium-ion batteries
(LIBs) are important power sources for portable electronics and electric cars, as they are more performant than other conventional batteries. However, LIBs raise concerns pertaining
the use of transition-metal electrode materials and liquid electrolytes. Conventional LiCoO2 cathodes and graphite anodes have limited energy density, while transition-metal oxide
cathodes pose environmental concerns. Liquid electrolytes are volatile and flammable, constituting a serious safety issue as they may lead to explosions if internal short-circuits give
rise to thermal runways with oxygen release. The overarching objective of this project is to explore alternative solutions to address these LIBs issues using redox-active Metal-
Organic Frameworks (MOFs) as the electrode materials, and solid Li-glass as the electrolyte. These MOFs are promising crystalline porous electrode materials for energy storage due
to their low solubility, high stability, high ionic conductivity, and versatility to tune by chemical design the electrode parameters (capacity and working potential). Since most MOFs
are insulators, a main challenge is to design MOFs exhibiting high electrical conductivity and stability to enhance the specific capacity and rate performance. This project aims at the
design and synthesis of a new family of conductive and highly stable redox-active MOFs to be used as LIBs electrode materials. Construction of such MOFs comprises the judicious
choice and functionalization of electroactive organic building blocks to enhance the electrode's conductivity and capacity and establish novel structure-property relatio  |
Summary
One of the main concerns of modern society is reducing its dependence on fossil fuels. Due to their low cost and low environmental impact, electrical energy storage devices are
among the most promising alternatives to conventional fossil fuels, as the electricity generated from renewable sources may be efficiently stored. In particular, lithium-ion batteries
(LIBs) are important power sources for portable electronics and electric cars, as they are more performant than other conventional batteries. However, LIBs raise concerns pertaining
the use of transition-metal electrode materials and liquid electrolytes. Conventional LiCoO2 cathodes and graphite anodes have limited energy density, while transition-metal oxide
cathodes pose environmental concerns. Liquid electrolytes are volatile and flammable, constituting a serious safety issue as they may lead to explosions if internal short-circuits give
rise to thermal runways with oxygen release. The overarching objective of this project is to explore alternative solutions to address these LIBs issues using redox-active Metal-
Organic Frameworks (MOFs) as the electrode materials, and solid Li-glass as the electrolyte. These MOFs are promising crystalline porous electrode materials for energy storage due
to their low solubility, high stability, high ionic conductivity, and versatility to tune by chemical design the electrode parameters (capacity and working potential). Since most MOFs
are insulators, a main challenge is to design MOFs exhibiting high electrical conductivity and stability to enhance the specific capacity and rate performance. This project aims at the
design and synthesis of a new family of conductive and highly stable redox-active MOFs to be used as LIBs electrode materials. Construction of such MOFs comprises the judicious
choice and functionalization of electroactive organic building blocks to enhance the electrode's conductivity and capacity and establish novel structure-property relationships. The
focus is on the electrode's key parameters (capacity, working potential, stability and electrical conductivity) to increase the energy and power densities of the batteries. The
improvement of such properties relies on DFT calculations. The novelty of the project lies in the use of unexplored redox-active ligands in tandem with high-valence metals to obtain
electrodes with high specific capacity, electrical conductivity and stability. The construction of all-solid-state batteries combining the redox-active MOFs and Li-glass solid electrolyte
(which exhibits an ionic conductivity comparable to the liquid) will be accomplished for the first time. Profiting from their high specific capacity, redox-active MOFs will be constructed
from electroactive organic building blocks promising for energy storage applications but that present solubility problems in electrolyte as single molecules. Namely, anthraquinone
(AQ) and tetrathiafulvalene (TTF) linkers will be combined with high-valence metals to afford stable, high capacity, MOFs cathode and anode materials, respectively. Such
electroactive organic linkers will be synthesized via simple chemical reactions and characterized by spectroscopic techniques. Electroactive MOFs will be prepared by optimizing
various synthetic parameters to obtain crystalline and highly stable porous materials. Key physical properties, such as capacities, working potentials, electrical conductivity and
porosity, will be adjusted by fine-tuning the electroactive organic building blocks and by post-synthetic modifications. MOFs electronic structure will be investigated by theoretical
calculations, in order to improve the conductivity and, thus, the electrochemical performance of the ensuing electrode materials. Redox-active MOFs will be exfoliated or deposited as
thin films to be used as LIBs electrodes. The thin film's morphology and thickness will be controlled by adjusting the synthetic parameters and will have a direct impact on the key
physical properties of the electrodes. The influence of crystallinity and thickness on the MOFs electrical transport properties will be studied in order to increase the energy and power
densities of the electrodes. The interfaces and performance of the batteries will be characterized by Electrochemical cycling, Electrical Impedance Spectroscopy (EIS) and cyclic
voltammetry (CV). Solid-state NMR will study the ion dynamics (e.g., activation energies), correlating with the theoretical data and impedance spectroscopy. The project
multidisciplinary team has much experience on: synthesis of highly stable and electroactive MOFs (João Rocha, Manuel Souto), solid-state NMR (Luís Mafra), band structure
calculations of electroactive molecules and frameworks (Manuel Melle-Franco), electrical transport characterization (Helena Alves) and fabrication of Li batteries using solid
electrolyte (Helena Braga). |