Hydromineralurgy
Keywords |
Classification |
Keyword |
OFICIAL |
Technology and Applied Sciences |
Instance: 2009/2010 - 2S
Cycles of Study/Courses
Teaching language
Suitable for English-speaking students
Objectives
- Knowledge: Recall basic concepts related to material balance in biphasic systems (solid-liquid); General concepts of chemistry.
- Comprehension: Recognize, Express and identify the unit operations involved in a hydrometallurgical process.
- Application: To discriminate the field of application of different technologies: to select the most appropriate technology for a particular case.
- Analysis: To calculate the materials balance in steady-state using analytical, numerical and graphical methods for each unit operation.
- Synthesis: Create and organize coherent process flowsheets for each unit operation and for the process as a whole.
Evaluation: Compare different process alternatives.
Program
LEACHING: Introduction: Mass balances – General principles. The diffusion - Fick Laws. Basic concepts: calculations involving biphasic systems (pulps) and extraction recovery. Leaching theory: diffusional and chemical control. Effect of agitation, temperature, concentration, phase ratio and interface geometry. Dynamic Leaching. Heap leaching. In-situ leaching. Bio-leaching. Pressure leaching. Electro-leaching. Examples: Hydrometallurgy of gold, aluminium, copper and uranium.
SOLID-LIQUID SEPARATION: Introduction and objectives. Continuous washing: by repulping using either thickeners or filters in a counter-current arrangement. Continuous washing with diffusion in counter-current arrangements. Filtration: basic equation of filtration; selection and design of a filter. Description of the main types of filters. Clarification, Flocculation and coagulation.
ENRICHMENT AND PURIFICATION: Ion exchange: Equilibrium and isotherms. Reaction kinetics. Ion Exchange in a fixed bed. Elution. Poisons. Basic concepts in a continuous ion exchange process. Technology
Adsorption by activated carbon. Properties. Mechanisms of adsorption in activated carbon. Its preparation. Stripping. Technology. Applications.
Solvent Extraction: Basic theory. Extraction systems: (a) chelating extractants, (b) acidic extractants, (c) systems involving ionic association (d) systems involving solvatation. Composition of the organic phase. Extraction technology. Number of stages. Equipment.
Finishing: Ionic Precipitation: formation of a precipitate, aggregation, orientation and supersaturation. Nucleation. Co-precipitation by adsorption, formation of solid solutions and occlusion.
Crystallization, cementation, gaseous precipitation and electrolysis.
Teaching methods and learning activities
Theoretical Lessons: Main concepts and its technological application;
Application Classes - Resolution of selected problems
Evaluation Type
Distributed evaluation with final exam
Assessment Components
Description |
Type |
Time (hours) |
Weight (%) |
End date |
Attendance (estimated) |
Participação presencial |
48,00 |
|
|
|
Total: |
- |
0,00 |
|
Eligibility for exams
Students are obliged to attend at least 75% of all the classes.
Calculation formula of final grade
Through final examination(s).
Examinations or Special Assignments
Not applicable.
Special assessment (TE, DA, ...)
Not applicable.
Classification improvement
Second final examination.