A new approach for the estimation of sublimation enthalpies and vapor pressures of crystalline benzene derivatives

• Tipo: Artigo em Revista Científica Internacional
• Data: 2013

Autores

Manuel J S Monte (Autor) FCUP; Ana R R P Almeida (Autor) Outra

Revista

Título: Structural Chemistry

Vol. 24

Páginas: 2001-2016

ISSN: 1040-0400

Editora: Springer Nature

Indexação

ISI Web of Knowledge - 26 Citações

Scopus - 26 Citações

Classificação Científica

FOS: Ciências exactas e naturais > Química

Outras Informações

ID Authenticus: P-006-JBD

DOI: 10.1007/s11224-013-0291-4

Abstract (EN): This work presents a new approach for estimating sublimation enthalpies and vapor pressures of substituted benzenes. Proposed estimating equations were based on a collection of selected literature results of vapor pressures of ca. 240 benzene derivatives attached with 30 different substituents. Compared to experimental results, best estimates are obtained from the equations that include the temperature of fusion. A review of the results determined for substituted benzenes using two different calorimetric techniques shows that the results of enthalpies of sublimation derived from vapor pressures seem to be more reliable than those derived from the calorimetric techniques.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 16