Single and Multicomponent Sorption of CO2, CH4 and N-2 in a Microporous Metal-Organic Framework

• Tipo: Artigo em Revista Científica Internacional
• Data: 2008

Autores

Barcia, PS (Autor) Outra; Bastin, L (Autor) Outra; Hurtado, EJ (Autor) Outra; Silva, JAC (Autor) Outra; Alírio Rodrigues (Autor) FEUP; Chen, BL (Autor) Outra

Revista

Título: Separation Science and Technology

Vol. 43 Nº 8

Páginas: 3494-3521

ISSN: 0149-6395

Editora: Taylor & Francis

Indexação

ISI Proceedings

ISI Web of Knowledge - 27 Citações

Scopus - 31 Citações

COMPENDEX

Classificação Científica

FOS: Ciências da engenharia e tecnologias > Engenharia química

CORDIS: Ciências Tecnológicas > Engenharia > Engenharia química

Outras Informações

ID Authenticus: P-004-4T3

DOI: 10.1080/01496390802282347

Abstract (EN): Single and multicomponent fixed-bed adsorption of CO2, N-2, and CH4 on crystals of MOF-508b has been studied in this work. Adsorption equilibrium was measured at temperatures ranging from 303 to 343 K and partial pressures up to 4.5 bar. MOF-508b is very selective for CO2 and the loadings of CH4 and N-2 are practically temperature independent. The Langmuir isotherm model provides a good representation of the equilibrium data. A dynamic model based on the LDF approximation for the mass transfer has been used to describe with good accuracy the adsorption kinetics of single, binary and ternary breakthrough curves. It was found that the intra-crystalline diffusivity for CO2 is one order of magnitude faster than for CH4 and N-2.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 28