Highly integrated flow assembly for automated dynamic extraction and determination of readily bioaccessible chromium(VI) in soils exploiting carbon nanoparticle-based solid-phase extraction

• Tipo: Artigo em Revista Científica Internacional
• Data: 2011

Autores

Maria Rosende (Autor) Outra; Manuel Miro (Autor) Outra; Marcela A Segundo (Autor) FFUP; Jose L F C Lima (Autor) FFUP; Victor Cerda (Autor) Outra

Revista

Título: Analytical and Bioanalytical Chemistry

Vol. 400 Nº 7

Páginas: 2217-2227

ISSN: 1618-2642

Editora: Springer Nature

Indexação

ISI Web of Knowledge - 20 Citações

ISI Web of Science

Scopus - 21 Citações

Classificação Científica

FOS: Ciências exactas e naturais > Química

CORDIS: Ciências Físicas > Química > Química analítica

Outras Informações

ID Authenticus: P-002-R1A

DOI: 10.1007/s00216-011-4954-y

Resumo (PT): An automated dynamic leaching test integrated in a portable flow-based setup is herein proposed for reliable determination of readily bioaccessible Cr(VI) under worst-case scenarios in soils containing varying levels of contamination. The manifold is devised to accommodate bi-directional flow extraction followed by processing of extracts via either in-line clean-up/preconcentration using multi-walled carbon nanotubes or automatic dilution at will, along with Cr(VI) derivatization and flow-through spectrophotometric detection. The magnitude of readily mobilizable Cr(VI) pools was ascertained by resorting to water extraction as promulgated by current standard leaching tests. The role of carbon nanomaterials for the uptake of Cr(VI) in soil leachates and the configuration of the packed column integrated in the flow manifold were investigated in detail. The analytical performance of the proposed system for in vitro bioaccessibility tests was evaluated in chromium-enriched soils at environmentally relevant levels and in a standard reference soil material (SRM 2701) with a certified value of total hexavalent chromium. The automated method was proven to afford unbiased assessment of water-soluble Cr(VI) in soils as a result of the minimization of the chromium species transformation. By combination of the kinetic leaching profile and a first-order leaching model, the water-soluble Cr(VI) fraction in soils was determined in merely 6 h against >24 h taken in batchwise steady-state standard methods. <br> <br> Keywords Hexavalent chromium – Bioaccessibility test – Soil – Automation – Miniaturization – Carbon nanoparticles <br> <a target="_blank" href="http://www.springerlink.com/content/g7061805m8632673/ "> Texto integral </a> <br> <br>

Abstract (EN): An automated dynamic leaching test integrated in a portable flow-based setup is herein proposed for reliable determination of readily bioaccessible Cr(VI) under worst-case scenarios in soils containing varying levels of contamination. The manifold is devised to accommodate bi-directional flow extraction followed by processing of extracts via either in-line clean-up/preconcentration using multi-walled carbon nanotubes or automatic dilution at will, along with Cr(VI) derivatization and flow-through spectrophotometric detection. The magnitude of readily mobilizable Cr(VI) pools was ascertained by resorting to water extraction as promulgated by current standard leaching tests. The role of carbon nanomaterials for the uptake of Cr(VI) in soil leachates and the configuration of the packed column integrated in the flow manifold were investigated in detail. The analytical performance of the proposed system for in vitro bioaccessibility tests was evaluated in chromium-enriched soils at environmentally relevant levels and in a standard reference soil material (SRM 2701) with a certified value of total hexavalent chromium. The automated method was proven to afford unbiased assessment of water-soluble Cr(VI) in soils as a result of the minimization of the chromium species transformation. By combination of the kinetic leaching profile and a first-order leaching model, the water-soluble Cr(VI) fraction in soils was determined in merely 6 h against > 24 h taken in batchwise steady-state standard methods.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 11