Low temperature glycerol steam reforming over a Rh-based catalyst combined with oxidative regeneration

• Tipo: Artigo em Revista Científica Internacional
• Data: 2019

Autores

Joel M. Silva (Autor) FEUP; Lucília S. Ribeiro (Autor) FEUP; José Melo Orfão (Autor) FEUP; Soria, M. (Autor) FEUP; Luís M. Madeira (Autor) FEUP

Revista

Título: International Journal of Hydrogen Energy

Vol. 44 Nº 5

Páginas: 2461-2473

ISSN: 0360-3199

Editora: Elsevier

Indexação

ISI Web of Knowledge - 20 Citações

Scopus - 22 Citações

Projetos Associados

LEPABE-2-ECO-INNOVATION - LEPABE-2-ECO-INNOVATION

Outras Informações

ID Authenticus: P-00Q-1VM

DOI: 10.1016/j.ijhydene.2018.11.234

Abstract (EN): A Rh on alumina catalyst was tested for glycerol steam reforming at 673 K, 4.5 bar and molar water/glycerol feed ratio (WGFR) of 19. Even though a conversion of glycerol into carbon-containing gaseous products of around 73% was observed at the beginning of the reaction, a progressive deactivation was noticed afterwards, less than 40% of glycerol being converted into carbon-containing gas products after 4 h of time-on-stream. On the other hand, the total glycerol conversion remained above 99% during the same period, thus indicating the increasing formation of coke and/or liquid products over time. The total glycerol conversion started to decrease more pronouncedly only after 6 h, reaching a value of approximately 92% after 13 h. SEM/EDS analysis of the used catalyst showed the presence of carbon deposits, Raman spectroscopy evidencing the dominant presence of amorphous carbon structures. Therefore, oxidative regeneration with air at 773 K was carried out. This temperature proved to be enough to gasify all removable coke (according to temperature-programmed oxidation results). After regeneration, almost complete recovery of catalytic performance was observed. In fact, maximum H-2 yields between 2.1 and 2.6 mol.mol(fed glycerol)(-1) were observed for the reaction cycles performed with intermediate oxidative regenerations. By combining glycerol steam reforming with periodic oxidative regeneration of the catalyst, superior average performance, compared to the case where no oxidative regeneration was used, was attained.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 13