Microwave-assisted headspace solid-phase microextraction to quantify polycyclic aromatic hydrocarbons in pine trees

• Tipo: Artigo em Revista Científica Internacional
• Data: 2012

Autores

Nuno Ratola (Autor) FEUP; Paulo Herbert (Autor) Outra; Arminda Alves (Autor) FEUP

Revista

Título: Analytical and Bioanalytical Chemistry

Nº de Série 6 Vol. 403

Páginas: 1761-1769

ISSN: 1618-2642

Editora: Springer Nature

Indexação

ISI Web of Knowledge - 7 Citações

ISI Web of Science

Scopus - 11 Citações

Classificação Científica

FOS: Ciências exactas e naturais > Química

Projetos Associados

SAFEPINE - SAFEPINE - Avaliação da contaminação de pinheiros por poluentes emergentes

Outras Informações

ID Authenticus: P-002-9PE

DOI: 10.1007/s00216-012-5962-2

Abstract (EN): A methodology for the extraction and quantification of 16 polycyclic aromatic hydrocarbons (PAHs) based on microwave-assisted extraction coupled with headspace solid-phase microextraction followed by gas chromatography/mass spectroscopy was validated for needles and bark of two pine species ( Ait. and L.). The limits of detection were below 0.92 ng g(-1) (dry weight) for needles and below 0.43 ng g(-1) (dw) for bark. Recovery assays were performed with two sample masses spiked at three levels and the overall mean values were between 70 and 110 % for and 75 and 129 % for . In the first species, the increase in sample mass lowered the recoveries slightly for most PAHs, whereas for the second, the recoveries were higher for the needles. Naturally contaminated samples from 4 sites were analysed, with higher levels for urban sites (1,320 and 942 ng g(-1) (dw) vs. 272 and 111 ng g(-1) (dw) for needles and 696 and 488 ng g(-1) (dw) vs. 270 and 103 ng g(-1) (dw) for bark) than for rural ones and also for samples over . It is also shown that gas-phase PAHs are predominant in the needles (over 65 % of the total PAHs) and that the incidence for particulate material in bark, reaching 40 % as opposed to a maximum below 20 % for the needles. The method has proved to be fit and improved some of the existing approaches, on the assessment of particulate PAHs and bark levels.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 9