Phenomenological Understanding of Hematite Photoanode Performance

• Type: Article in International Scientific Journal
• Date: 2021-04-22

Authors

João Pina (Author) Other; Dias, P. (Author) FEUP; Carlos Serpa (Author) Other; João Azevedo (Author) Other; Adélio Mendes (Author) FEUP; João Melo (Author) Other

Journal

Title: Journal of Physical Chemistry C

Vol. 125 No. 15

Pages: 8274-8284

ISSN: 1932-7447

Publisher: American Chemical Society

Indexing

ISI Web of Knowledge - 0 Citations

Scopus - 0 Citations

Scientific classification

CORDIS: Physical sciences > Chemistry

FOS: Engineering and technology > Chemical engineering

Other information

Authenticus ID: P-00T-WGX

DOI: 10.1021/acs.jpcc.0c11420

Abstract (EN): The effect of the structural and electronic properties of hematite photoanodes on the charge carrier dynamics was investigated by photoelectrochemistry and transient absorption spectroscopy (TAS). Hematite photoelectrodes were prepared by spray pyrolysis and hydrothermal methods for obtaining films with different thicknesses, morphologies, doping agents, and surface treatments. TAS analyses were performed using standalone photoelectrodes, a three-electrode configuration and in operando. TAS studies revealed that there is a significant electron-hole recombination within the first few hundred picoseconds and smaller amplitude of longer-lived charge carriers, which are responsible for the generated photocurrent observed in photoelectrochemical measurements. The best performing photoelectrodes are Sn-doped hematite thin film annealed at 800 degrees C and coated with IrO2/RuO2 co-catalyst and the Ti-doped hematite nanowires. The effect of surface treatments, i.e., high-temperature annealing responsible for Sn intrinsic doping and co-catalyst coating, on the electron-hole recombination dynamics is negligible at the picosecond time scale. The TAS studies showed a slower electron-hole recombination after Ti incorporation, increased electron density, and enlarged surface area.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 11