When theory and experiment hold hands: The thermochemistry of gamma-pyrone derivatives

• Tipo: Artigo em Revista Científica Internacional
• Data: 2011

Autores

Clara C S Sousa (Autor) FCUP; Agostinha A R Matos (Autor) FCUP; Victor M F Morais (Autor) ICBAS

Revista

Título: Journal of Chemical Thermodynamics

Vol. 43 Nº 2

Páginas: 1159-1163

ISSN: 0021-9614

Editora: Elsevier

Indexação

ISI Web of Knowledge - 2 Citações

Scopus - 1 Citação

Classificação Científica

FOS: Ciências da engenharia e tecnologias > Engenharia mecânica

Outras Informações

ID Authenticus: P-002-PHN

DOI: 10.1016/j.jct.2011.02.021

Abstract (EN): In this work, we have determined the experimental standard (p degrees = 0.1 MPa) molar enthalpies of formation, in the gas phase, of 2,6-dimethy1-4-pyrone -(261.5 +/- 2.6) kJ . mol(-1) and 2-ethy1-3-hydroxy-4-pyrone -(420.9 +/- 2.8) kJ . mol(-1). These values were obtained by combining the standard molar enthalpy of formation in the condensed phase, derived from combustion experiments in oxygen, at T = 298.15 K, in a static bomb calorimeter, with the standard molar enthalpy of sublimation, at T = 298.15 K, obtained by Calvet microcalorimetry. Additionally, high-level density functional theory calculations using the B3LYP hybrid exchange-correlation energy functional with extended basis sets have been performed for these two compounds. Good agreement was obtained between the experimental and computational results. Using the same methodology, we calculated the standard molar enthalpy of formation of gaseous 2-methyl-3-hydroxy-4-pyrone.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 5