Generalized linear driving force approximation for adsorption of multicomponent mixtures

• Tipo: Artigo em Revista Científica Internacional
• Data: 2006

Autores

Cruz, P (Autor) Outra; Magalhaes, FD (Autor) FEUP; Mendes, A (Autor) FEUP

Revista

Título: Chemical Engineering Science

Vol. 61

Páginas: 3519-3531

ISSN: 0009-2509

Editora: Elsevier

Indexação

ISI Web of Knowledge - 24 Citações

ISI Web of Science

Scopus - 31 Citações

Classificação Científica

FOS: Ciências da engenharia e tecnologias > Engenharia química

CORDIS: Ciências Tecnológicas

Outras Informações

ID Authenticus: P-004-KAW

DOI: 10.1016/j.ces.2006.01.001

Abstract (EN): This work deals with the development of efficient numerical tools for the solution of diffusion dominated parabolic partial differential equations. This study finds its application in the modeling of the intraparticle mass balance necessary for describing dynamic adsorption processes. The orthogonal collocation method is proposed as the basis for developing generalized linear driving force approximations for adsorption and desorption of multicomponent mixtures in a single particle, independently of the mass transport model adopted. Based on this approach, it was possible to derive some approximations previously obtained from the analytical series of the homogeneous diffusion equation. Orthogonal collocation is also compared to other numerical methods found in the literature, using both the homogeneous diffusion and the dusty-gas mass transport models. The results show that orthogonal collocation is the more consistent approach.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 13