Acoustic, volumetric and osmotic properties of binary mixtures containing the ionic liquid 1-butyl-3-methylimidazolium dicyanamide mixed with primary and secondary alcohols

• Tipo: Artigo em Revista Científica Internacional
• Data: 2012

Autores

Noélia Calvar (Autor) FEUP; Emilio J. González (Autor) FEUP; Dominguez, A (Autor) Outra; Maria Eugénia Macedo (Autor) FEUP

Revista

Título: Journal of Chemical Thermodynamics

Vol. 50

Páginas: 19-29

ISSN: 0021-9614

Editora: Elsevier

Indexação

ISI Web of Knowledge - 26 Citações

Scopus - 29 Citações

Classificação Científica

CORDIS: Ciências Tecnológicas

FOS: Ciências da engenharia e tecnologias

Projetos Associados

LA 20 - Projeto Estratégico-LA 20 - 2011-2012

Outras Informações

ID Authenticus: P-002-8TG

DOI: 10.1016/j.jct.2012.02.007

Abstract (EN): In this paper, densities and speeds of sound for five binary systems {alcohol + 1-butyl-3-methylimidazolium dicyanamide} were measured from T = (293.15 to 323.15) K and atmospheric pressure. From these experimental data, apparent molar volume and apparent molar isentropic compression have been calculated and fitted to a Redlich-Meyer type equation. This fit was also used to calculate the apparent molar volume and apparent molar isentropic compression at infinite dilution for the studied binary mixtures. Moreover, the osmotic and activity coefficients and vapor pressures of these binary mixtures were also determined at T = 323.15 K using the vapor pressure osmometry technique. The experimental osmotic coefficients were correlated using the Extended Pitzer model of Archer. The mean molal activity coefficients and the excess Gibbs free energy for the studied mixtures were calculated from the parameters obtained in the correlation. (c) 2012 Published by Elsevier Ltd.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 11