Brown macro-algae as natural cation exchangers for the treatment of zinc containing wastewaters generated in the galvanizing process

• Tipo: Artigo em Revista Científica Internacional
• Data: 2016

Autores

Tatiana A. Pozdniakova (Autor) FEUP; Luciana P Mazur (Autor) FEUP; Rui A. R. Boaventura (Autor) FEUP; Vítor J. P. Vilar (Autor) FEUP

Revista

Título: Journal of Cleaner Production

Vol. 119

Páginas: 38-49

ISSN: 0959-6526

Editora: Elsevier

Indexação

ISI Web of Knowledge - 18 Citações

ISI Web of Science

Scopus - 0 Citações

INSPEC

Classificação Científica

CORDIS: Ciências Tecnológicas > Tecnologia > Tecnologia ambiental

FOS: Ciências da engenharia e tecnologias > Engenharia do ambiente

Projetos Associados

LA 20 - PROJECTO ESTRATÉGICO - LA 20 - 2013-2014

ALGAEVALUE - Valorização de macroalgas marinhas na separação e recuperação de iões metálicos tóxicos presentes em água

LSRE-LCM - Laboratório de Processos de Separação e Reação - Laboratório de Catálise e Materiais

Outras Informações

ID Authenticus: P-00K-89J

DOI: 10.1016/j.jclepro.2016.02.003

Abstract (EN): In this study, brown macro-algae harvested from the north coast of Portugal, Laminaria hyperborea, Fucus spiralis, Pelvetia caniculata and Ascophyllum nodosum, were used as natural cation exchangers for the treatment of zinc-containing rinse waters generated in the galvanizing process. The zinc wastewater is characterized by a high conductivity (1.5 mS/cm), a low organic content and a zinc concentration of 10 mg/L, being approximately 80% and 20% in the form of Zn2+ and ZnSO4(aq), respectively. Although the ion-exchange capacity of the four macro-algae is similar (2.2-2.4 mEq/g), mainly associated with the presence of weak acidic carboxylic and strong acidic sulfonic groups, L. hyperborea showed a higher selectivity for zinc ions. The uptake capacity for zinc ions is highly affected by the galvanic wastewater matrix, when compared with the performance using a pure zinc solution. Zinc uptake equilibrium, on all the natural cation exchangers, was well described by a linear relationship. Cation exchange kinetic was adequately represented by a mass transfer model, considering a linear driving force model for intraparticle diffusion. Na-loaded alga showed a higher affinity for zinc ions when compared with Ca-loaded alga and raw alga. HCl, HNO3, H2SO4 and CaCl2 eluents were tested for zinc displacement from exhausted algae. HNO3 reached an elution efficiency of 100% in less time than the other eluents tested. After the acid elution, the resin was converted to Na or Ca form (Na- or Ca-H-loaded biomass), using NaCI and CaCl2 solutions. Although the regenerated alga in the form of sodium showed a higher affinity for zinc ions, its physical deterioration after Na loading may affect its application in a full-scale treatment.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 12