THE TEMPERATURE-COEFFICIENT OF THE POTENTIAL OF ZERO CHARGE OF STEPPED FACES OF GOLD IN CONTACT WITH AQUEOUS PERCHLORIC-ACID SOLUTIONS

• Tipo: Artigo em Revista Científica Internacional
• Data: 1993

Autores

SILVA, F (Autor) FCUP; SOTTOMAYOR, MJ (Autor) FCUP; MARTINS, A (Autor) Outra

Revista

Título: Journal Of Electroanalytical Chemistry

Vol. 360

Páginas: 199-210

ISSN: 1572-6657

Editora: Elsevier

Indexação

ISI Web of Knowledge - 11 Citações

Scopus - 9 Citações

Classificação Científica

FOS: Ciências exactas e naturais > Química

Outras Informações

ID Authenticus: P-001-MEB

DOI: 10.1016/0022-0728(93)87013-l

Abstract (EN): Potentials of zero charge, E(sigma=0), and the temperature coefficients of E(sigma=0) for stepped surfaces of sold single crystals (511), (533), (331) and (311) were obtained from the minimum of the differential capacity curve in dilute HClO4 solutions. The results are compared with those obtained for the low index faces and dilute in terms of the effect of the surface density of steps and the step orientation. The possible relevance of the effect of steps on the interaction of water with gold surfaces is discussed.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 12