The influence of the halogen atoms and acetyl group on vapour pressures and related properties of the p-haloacetophenones

• Tipo: Artigo em Revista Científica Internacional
• Data: 2016

Autores

Almeida, ARRP (Autor) FCUP; Manuel J S Monte (Autor) FCUP

Revista

Título: Journal of Chemical Thermodynamics

Vol. 92

Páginas: 118-125

ISSN: 0021-9614

Editora: Elsevier

Indexação

ISI Web of Knowledge - 15 Citações

Scopus - 15 Citações

Outras Informações

ID Authenticus: P-00G-NP3

DOI: 10.1016/j.jct.2015.09.004

Abstract (EN): This work reports experimental vapour pressures at different temperatures of four halogenated acetophenones. The liquid phase vapour pressures of p-fluoro and p-chloro acetophenones were measured, respectively, across the temperatures ranges (255.1 to 310.2) K and (271.6 to 335.0) K, using a static method based on capacitance diaphragm manometers. This experimental technique was also used to measure the vapour pressures of both (crystalline and liquid) condensed phases of p-bromo-and p-iodoacetophenones, respectively, through the temperature intervals (295.3 to 378.4) K and (313.1 to 402.0) K. The temperatures and molar enthalpies and entropies of fusion of the four p-halogenated acetophenones were determined using differential scanning calorimetry. The standard molar enthalpies, entropies and Gibbs energies of sublimation and of vaporisation, at selected reference temperatures, were derived from the experimental results. The contributions of the acetyl group and of the constituent halogen atoms to these thermodynamic properties were also predicted through correlation equations.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 8