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Oscillations in the oxidation of MIBK over a Pt/HFAU catalyst: role of coke combustion

Title
Oscillations in the oxidation of MIBK over a Pt/HFAU catalyst: role of coke combustion
Type
Article in International Scientific Journal
Year
2003
Authors
Tsou, J
(Author)
Other
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Magnoux, P
(Author)
Other
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Guisnet, M
(Author)
Other
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José Melo Orfão
(Author)
FEUP
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José Luis Figueiredo
(Author)
FEUP
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Journal
Vol. 4
Pages: 651-656
ISSN: 1566-7367
Publisher: Elsevier
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Publicação em ISI Web of Science ISI Web of Science
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Other information
Authenticus ID: P-000-E75
Abstract (EN): The catalytic oxidation of methyl-isobutyl-ketone (MIBK) in low concentration (1340 ppm) was investigated over a Pt/HFAU catalyst. Two main reactions were observed: total oxidation into CO2 and the formation of non-desorbed compounds ("coke"). The conversion into these products depends on the reaction temperature, high temperatures being favourable to the conversion into CO2 and unfavourable to the conversion into coke. Oscillations in the conversion into CO2 were observed at specific temperatures, which were explained by coke combustion.
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 6
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