Effect of nanostructure on the supercapacitor performance of activated carbon xerogels obtained from hydrothermally carbonized glucose-graphene oxide hybrids

• Type: Article in International Scientific Journal
• Date: 2016

Authors

M. Enterría (Author) FEUP; F. J. Martín-Jimeno (Author) Other; F. Suárez-García (Author) Other; J. I. Paredes (Author) Other; M. F. R. Pereira (Author) FEUP; J. I. Martins (Author) FEUP; A. Martínez-Alonso (Author) Other; J. M. D. Tascón (Author) Other; J. L. Figueiredo (Author) FEUP

Journal

Title: Carbon

Vol. 105

Pages: 474-483

ISSN: 0008-6223

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 38 Citations

ISI Web of Science

Scopus - 51 Citations

INSPEC

Associated Projects

LSRE-LCM - Laboratório de Processos de Separação e Reação - Laboratório de Catálise e Materiais

AIProcMat@N2020 - Advanced Industrial Processes and Materials for a Sustainable North Region of Portugal2020

Other information

Authenticus ID: P-00K-SS7

DOI: 10.1016/j.carbon.2016.04.071

Abstract (EN): Activated carbon xerogels with a cellular morphology were obtained from hydrothermally carbonized glucose-graphene oxide (GO) hybrids and tested as supercapacitor electrodes. The effect of the chemical activation (using KOH) on the nanometer-scale morphology, local structure, porous texture and surface chemistry of the resulting carbon materials was investigated and correlated with their electrochemical behaviour. The electrochemical performance of the activated xerogels was studied in a three-electrode cell using 1 M H2SO4 as the electrolyte. The results underlined the relevant role played by the xerogel nanomorphology; more specifically, xerogels with cellular structures exhibiting well-connected, continuous and very thin (∿5-15 nm) carbon walls (prepared with lower amounts of activating agent) favored ionic diffusion and electronic conduction compared to materials with broken, thicker walls (obtained from higher amounts of activating agent). The effect of nanomorphology and local structure was also made apparent when the xerogels were used as actual supercapacitor electrodes. Particularly, a symmetric capacitor assembled from a carbon xerogel with very thin walls and relatively high graphitic character delivered a much higher specific capacitance than that of a commercial activated carbon (223 vs 153 F g-1 at 100 mA g-1) as well as a significantly improved retention of capacitance at high current densities.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 10