Tunning pore filling of anodic alumina templates by accurate control of the bottom barrier layer thickness

• Tipo: Artigo em Revista Científica Internacional
• Data: 2011

Autores

sousa, c. t. (Autor) Outra; leitao, d. c. (Autor) Outra; proenca, m. p. (Autor) FCUP; apolinario, a. (Autor) Outra; correia, j. g. (Autor) Outra; ventura, j. (Autor) FCUP; araujo, j. p. (Autor) FCUP

Revista

Título: Nanotechnology

Vol. 22

Página Final: 315602

ISSN: 0957-4484

Editora: Institute of Physics Publishing

Indexação

ISI Web of Knowledge - 68 Citações

Scopus - 69 Citações

Outras Informações

ID Authenticus: P-002-NSZ

DOI: 10.1088/0957-4484/22/31/315602

Abstract (EN): The role of the alumina barrier layer thickness (delta(b)) on the growth of Ni nanowires (NWs) in porous anodic alumina (PAA) has been revealed. By varying the final anodization voltage to form dendrites at the bottom of the nanoporous structure, we are able to optimize delta(b) (in the 2-16 nm range), allowing us to obtain a Ni pore filling percentage (f(p)) of almost 100% for delta(b) = 10 nm. However, deviations from this optimal delta(b)-value led to a strong decrease of f(p). Moreover, an increase of the electrodeposition efficiency (EE) and NW homogeneity was also verified for delta(b) up to 10 nm. Such increase in nominal delta(b) leads to a consistent growth rate in all pores and consequently a complete and uniform nanopore filling. On the other hand, the decrease in electrodeposition efficiency visible for delta(b) > 10 nm is related with hydrogen evolution and dielectric breakdown of the insulator layer due to the required high deposition voltages. Non-uniform NW growth is then visible, with the consequent decrease in f(p). The control of the pore filling and length homogeneity of the fabricated 1D metallic nanostructures, combined with the ability to adjust the pore dimensions of PAA, can bring novel approaches for the fabrication of nano-objects and thus exciting new applications.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 6