Improved Interfacial Electron Dynamics with Block Poly(4-vinylpyridine)-Poly(styrene) Polymers for Efficient and Long-Lasting Dye-Sensitized Solar Cells

• Tipo: Artigo em Revista Científica Internacional
• Data: 2024-07-20

Autores

Daniela Rodrigues (Autor) FEUP; Carlos M. R. Abreu (Autor) Outra; Frédéric Sauvage (Autor) Outra; Jorge F. J. Coelho (Autor) Outra; Arménio C. Serra (Autor) Outra; Dzmitry Ivanou (Autor) FEUP; Adélio Mendes (Autor) FEUP

Revista

Título: ACS Applied Polymer Materials

Páginas: 8939-8949

Editora: American Chemical Society

Indexação

ISI Web of Knowledge - 0 Citações

Scopus - 0 Citações

Outras Informações

ID Authenticus: P-011-3WX

DOI: 10.1021/acsapm.4c01238

Abstract (EN): Dye-sensitized solar cells (DSSCs) have recently entered the market for indoor photovoltaics. Fast electron injection from dye to titania, the lifetime of the excited dye, and the suppression of back electron recombination at the photoanode/electrolyte interface are crucial for a high photocurrent conversion efficiency (PCE). This study presents block copolymers of poly(4-vinylpyridine) and poly(styrene)-P4VP(67)-b-PSt(x (x=23;61)) as efficient accelerators of electron injection from dye to titania with extended lifetime excited states and long-lasting back electron recombination suppression. P4VP(67)-b-PSt(23) and P4VP(67)-b-PSt(61) rendered devices with PCEs of 10.0 and 9.8%, respectively, under AM 1.5G light; PCEs of 19.4 and 16.4% under 1000 lx LED light were attained. Copolymers provided a stable PCE with the two most popular I-3(-)/3I(-) electrolytes based on ACN and 3-methoxypropionitrile solvents; PCE history was tracked in the dark and under 1000 h of continuous light soaking with passive load according to ISOS-D1 and ISOS-L2 aging protocols, respectively. The impact of the polymer molecular structure on electron recombination, charge injection, dye anchoring, light absorption, photocurrent generation, and PCE and the long-term history of photovoltaic metrics are discussed.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 11