Design and development of a multichannel potentiometer for monitoring an electrode array and its application in f ow analysis

• Tipo: Artigo em Revista Científica Internacional
• Data: 2002

Autores

Jarbas J. R. Rohwedder (Autor) Outra; Celio Pasquini (Autor) Outra; Ivo M. Raimundo Jr (Autor) Outra; M. Conceição B. S. Montenegro (Autor) FFUP; Alberto N. Araújo (Autor) FFUP; Cristina M. C. M. Couto (Autor) Outra

Revista

Título: Journal of Automated Methods and Management in Chemistry

Vol. 24 Nº 4

Páginas: 105-110

ISSN: 1463-9246

Editora: HINDAWI PUBLISHING CORPORATION

Indexação

ISI Web of Science

Classificação Científica

FOS: Ciências médicas e da saúde > Outras ciências médicas

CORDIS: Ciências da Saúde

Outras Informações

Resumo (PT): A versatile potentiometer that works with electrode arrays in flow injection and/or monosegmented flow systems is described. The potentiometer is controlled by a microcomputer that allows individual, sequential multiplexed or random accesses to eight electrodes while employing only one reference electrode. The instrument was demonstrated by monitoring an array of seven flow-through ion-selective electrodes for Ag+ and for three electrodes for Cl-, Ca2+ and K+. The figures of merit of the individual and multiplexed (summed) readings of the electrode array were compared. The absolute standard deviation of the measurements made by summing the potential of two or more electrodes was maintained constant, thus improving the precision of the measurements. This result shows that an attempt to combine the signals of the electrodes to produce a more intense signal in the Hadamard strategy is feasible and accompanied by a proportional improvement in the precision of individual measurements. The preliminary tests suggest that the system can allow for 270 determinations per hour, with a linear range from 1.0×10−2 to 1.0×10−4 mol l-1 for the three di¡erent analytes. Detection limits were estimated as 3.1×10−5 , 3.0×10−6 and 1.0×10−5 mol l-1 for Cl-, Ca2+ and K+, respectively. <br> <br> <a target="_blank" href="http://www.hindawi.com/journals/jammc/2002/450969.abs.html"> Texto integral </a> <br> <br>

Abstract (EN): A versatile potentiometer that works with electrode arrays in flow injection and/or monosegmented flow systems is described. The potentiometer is controlled by a microcomputer that allows individual, sequential multiplexed or random accesses to eight electrodes while employing only one reference electrode. The instrument was demonstrated by monitoring an array of seven flow-through ion-selective electrodes for Ag+ and for three electrodes for Cl-, Ca2+ and K+. The figures of merit of the individual and multiplexed (summed) readings of the electrode array were compared. The absolute standard deviation of the measurements made by summing the potential of two or more electrodes was maintained constant, thus improving the precision of the measurements. This result shows that an attempt to combine the signals of the electrodes to produce a more intense signal in the Hadamard strategy is feasible and accompanied by a proportional improvement in the precision of individual measurements. The preliminary tests suggest that the system can allow for 270 determinations per hour, with a linear range from 1.0×10−2 to 1.0×10−4 mol l-1 for the three di¡erent analytes. Detection limits were estimated as 3.1×10−5 , 3.0×10−6 and 1.0×10−5 mol l-1 for Cl-, Ca2+ and K+, respectively. <br> <br> <a target="_blank" href="http://www.hindawi.com/journals/jammc/2002/450969.abs.html"> Full text</a> <br> <br>

Idioma: Inglês

Tipo (Avaliação Docente): Científica