Activated carbon and ceria catalysts applied to the catalytic ozonation of dyes and textile effluents

• Tipo: Artigo em Revista Científica Internacional
• Data: 2009

Autores

P. C. C. Faria (Autor) FEUP; J. J. M. Órfão (Autor) FEUP; M. F. R. Pereira (Autor) FEUP

Revista

Título: Applied Catalysis B: Environmental

Vol. 88

Páginas: 341-350

ISSN: 0926-3373

Editora: Elsevier

Indexação

ISI Web of Knowledge - 98 Citações

ISI Web of Science

Scopus - 145 Citações

COMPENDEX

INSPEC

Classificação Científica

FOS: Ciências da engenharia e tecnologias > Outras ciências da engenharia e tecnologias

CORDIS: Ciências Tecnológicas

Outras Informações

ID Authenticus: P-003-K22

DOI: 10.1016/j.apcatb.2008.11.002

Abstract (EN): The application of catalytic ozonation processes for the decolourisation and mineralisation of coloured aqueous solutions was studied. One acid azo dye, Cl Acid Blue 113, and two reactive dyes, Cl Reactive Yellow 3 and Cl Reactive Blue 5, with azo and anthraquinone chromophores, respectively, were used as representative textile dyes. The catalytic activities of activated carbon, cerium oxide and a ceria-activated carbon composite were evaluated in the removal of the selected dyes. In all cases, with an initial dye concentration of 50 mg/L, a complete decolourisation was achieved by single ozonation in short reaction times (less than 10 min). The ceria-activated carbon composite allowed the highest removal of total organic carbon. For dye concentrations of 50 mg/L, mineralisation degrees of 100%, 98% and 97% were achieved with the composite after 2 h of reaction, respectively for Cl Reactive Blue 5, Cl Acid Blue 113 and Cl Reactive Yellow 3. The activity of the catalyst containing cerium was affected by the presence of carbonate and bicarbonate ions due to their scavenging effect towards hydroxyl radicals; for example the mineralisation degree of Cl Reactive Blue 5 (C(0) = 300 mg/L) after 120 min of reaction was only 63%, contrasting with the value of 85% obtained in the absence of carbonates. All the catalytic systems were evaluated in the treatment of textile effluents, collected before or after conventional biological treatment. Catalytic ozonation was proven to be effective when used as tertiary treatment for bio-treated effluents.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 10