Physicochemical properties of 2-alkyl-1-ethylpyridinium based ionic liquids

• Tipo: Artigo em Revista Científica Internacional
• Data: 2016

Autores

Rocha, MAA (Autor) Outra; Vilas, M (Autor) Outra; Rodrigues, ASMC (Autor) Outra; Tojo, E (Autor) Outra; Luis M N B F Santos (Autor) FCUP

Revista

Título: Fluid Phase Equilibria

Vol. 428

Páginas: 112-120

ISSN: 0378-3812

Editora: Elsevier

Indexação

ISI Web of Knowledge - 15 Citações

Scopus - 15 Citações

Outras Informações

ID Authenticus: P-00M-77P

DOI: 10.1016/j.fluid.2016.05.030

Abstract (EN): In this work, the effect of the alkyl chain size in 1-ethylpyridinium cation-based ionic liquids are used to explore the nanostructuration effect. Densities and viscosities and their dependence on temperature were measured for the 2-alkyl-l-ethylpyridinium bis(trifluoromethanesulfonyl)imide, [(CN-2C2Py)-C-2-C-1] [NTf2] (N = 4,5, 6, 7, 8, 9, 10, 11,12) ionic liquid series. Molar volume, thermal expansion coefficients, VET parameters, as well as, the energy barrier related to the fluid shear at T= 298.15 K, were derived. Highly precise measurements of the heat capacities, at T = 298.15 K, were performed using a drop calorimeter. In agreement with the previously studies based on the alkylimidazolium ionic liquids series, the studied thermophysical and transport properties of the series presents an indication that in the pyridinium based ionic liquids the nanostructuration is intensified after a critical alkyl length, [(C5C2Py)-C-2-C-1][NTf2]. The observed trend shift in the viscosity and heat capacities of the pyridinium ionic liquids is more pronounced in the pyridinium than in the imidazolium ionic liquids series.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 9