Thermodynamics of long-chain 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ionic liquids

• Tipo: Artigo em Revista Científica Internacional
• Data: 2016

Autores

Paulechka, E (Autor) Outra; Blokhin, AV (Autor) Outra; Rodrigues, ASMC (Autor) Outra; Rocha, MAA (Autor) Outra; Luis M N B F Santos (Autor) FCUP

Revista

Título: Journal of Chemical Thermodynamics

Vol. 97

Páginas: 331-340

ISSN: 0021-9614

Editora: Elsevier

Indexação

ISI Web of Knowledge - 25 Citações

Scopus - 25 Citações

Outras Informações

ID Authenticus: P-00K-87X

DOI: 10.1016/j.jct.2016.02.009

Abstract (EN): The heat capacities in the temperature range (5 to 370) K and the parameters of solid-phase transitions and fusion were determined for three [C(n)mim][NTf2] (n = 10, 14, 16) ILs. The temperature-dependent vapour pressures of [C(14)mim][NTf2] and [C(16)mim][NTf2] were measured with a Knudsen effusion apparatus combined with a quartz crystal microbalance. Thermodynamic properties of these compounds in the crystal, liquid, and gas states were derived from the obtained data. The results obtained in this work were combined to those available in the literature for the short-chain homologues to discuss regularities in thermodynamic properties of the series. While some properties demonstrate simple linear dependence on the alkyl chain length, a more complicated behaviour with strong non-linearity or a break at n = 6 is observed for others. Published by Elsevier Ltd.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 10