Mechanical characterization of polyhydroxyalkanoate and poly(lactic acid) blends

• Tipo: Artigo em Revista Científica Internacional
• Data: 2015

Autores

Loureiro, NC (Autor) Outra; Esteves, JL (Autor) FEUP; Viana, JC (Autor) Outra; Ghosh, S (Autor) Outra

Revista

Título: Journal of Thermoplastic Composite Materials

Nº de Série 0892-7057 Vol. 28

Páginas: 195-213

ISSN: 0892-7057

Editora: SAGE

Indexação

ISI Web of Knowledge - 4 Citações

Scopus - 8 Citações

Outras Informações

ID Authenticus: P-00A-6WT

DOI: 10.1177/0892705712475020

Abstract (EN): In this work, the mechanical behavior of polyhyroxyalkanoate (PHA)/poly(lactic acid) (PLA) blends is investigated in a wide range of compositions. The mechanical properties can be optimized by varying the PHA contents of the blend. The flexural and tensile properties were estimated by different models: the rule of mixtures, Kerner-Uemura-Takayanagi (KUT) model, Nicolai-Narkis model and Bela-Pukansky model. This study was aimed at investigating the adhesion between the two material phases. The results anticipate a good adhesion between both phases. Nevertheless, for low levels of incorporation of PHA (up to 30%), where PLA is expectantly the matrix, the experimental data seem to deviate from the perfect adhesion models, suggesting a decrease in the adhesion between both polymeric phases when PHA is the disperse phase. For the tensile modulus, a linear relationship is found, following the rules of mixtures (or a KUT model with perfect adhesion between phases) denoting a good adhesion between the phases over the composition range. The incorporation of PHA in the blend leads to a decrease in the flexural modulus but, at the same time, increases the tensile modulus. The impact energy of the blends varies more than 157% over the entire composition. For blends with PHA weight fraction lower than 50%, the impact strength of the blend is higher than the pure base polymers. The highest synergetic effect is found when the PLA is the matrix and the PHA is the disperse phase for the blend PHA/PLA of 30/70. The second maximum is found for the inverse composition of 70/30. PLA has a heat-deflection temperature (HDT) substantially lower than PHA. For the blends, the HDT increases with the increment in the percentage of the incorporation of PHA. With up to 50% PHA (PLA as matrix), the HDT is practically constant and equal to PLA value. Above this point (PHA matrix), the HDT of the polymer blends increases linearly with the percentage of addition of PHA.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 19