INFLUENCE OF ADSORPTION DESORPTION-KINETICS ON THE PERFORMANCE OF CHROMATOGRAPHIC PROCESSES USING LARGE-PORE SUPPORTS

• Tipo: Artigo em Revista Científica Internacional
• Data: 1992

Autores

Alírio Rodrigues (Autor) FEUP; RAMOS, AMD (Autor) Outra; José Miguel Loureiro (Autor) FEUP; DIAZ, M (Autor) Outra; LU, ZP (Autor) Outra

Revista

Título: Chemical Engineering Science

Vol. 47 Nº 15

Páginas: 4405-4413

ISSN: 0009-2509

Editora: Elsevier

Indexação

ISI Web of Knowledge - 33 Citações

Scopus - 32 Citações

Outras Informações

ID Authenticus: P-001-NYV

DOI: 10.1016/0009-2509(92)85118-u

Abstract (EN): Large-pore packings are being widely used for bioseparations, e.g. high-pressure liquid chromatography and also in some gas-phase applications. Most studies are based on the assumption of instantaneous equilibrium at the pore-solid interface. This paper shows how adsorption-desorption kinetics influences the performance of chromatographic processes measured by the height equivalent to a theoretical plate (HETP). A criterion is derived allowing us to predict when the assumption of instantaneous equilibrium at the pore-solid interface is valid.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 9