Aluminium Evaporation During Ceramic Crucible Induction Melting of Titanium Aluminides

• Tipo: Artigo em Livro de Atas de Conferência Internacional
• Data: 2013

Autores

Gomes, F (Autor) Outra; Barbosa, J (Autor) Outra; Carlos Silva Ribeiro (Autor) FEUP

Ata de Conferência Internacional

Título: ADVANCED MATERIALS FORUM VI, PTS 1 AND 2

Páginas: 697-702

6th International Materials Symposium (MATERIALS 2011)/15th Meeting of SPM

Guimaraes, PORTUGAL, APR 18-20, 2011

Indexação

ISI Web of Knowledge - 1 Citação

Scopus - 4 Citações

Outras Informações

ID Authenticus: P-005-3PP

DOI: 10.4028/www.scientific.net/msf.730-732.697

Abstract (EN): Melting TiAl based alloys in ceramic crucibles often leads to chemical contamination, alloy heterogeneity and non-metallic inclusions. The severity of such phenomena usually depends on the nature of crucible materials, the melting stock composition and the melting parameters, namely superheating time and temperature and melting pressure. Among the referred drawbacks, Al loss during melting is a critical aspect, as its concentration in TiAl based alloys has a very strong effect in their mechanical properties. Although a few studies of critical factors affecting the evaporation behaviour of Al during electron beam and induction skull melting of Ti-Al alloys had been carried out, until now no information was released on this subject for the ceramic crucible induction melting process. In this work a Ti-48Al alloy was induction melted in a zircon crucible with Y2O3 inner layer, using 50 and 100 degrees C superheating temperatures and 0, 60 and 90 second holding times, and poured into a graphite mould. The effect of different temperature/time combinations in the alloy composition, Al loss by evaporation and extent of the metal/crucible interaction was studied for different melting pressures. Al loss was found to increase significantly for melting pressures below around 10(-1) mbar, at a rate that increases as melting pressure decreases, until a maximum rate is reached, remaining constant for lower pressure levels. Metal/crucible interaction increased directly with the melting pressure and superheating time, leading to alloy contamination with yttrium and oxygen. For the experimental set-up and conditions used on this work, optimal superheating time/pressure combinations that lead to acceptable alloy composition and sanity have been identified.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 6