Abstract (EN):
Seven heat conduction calorimeters have been evaluated in terms of sensitivity and thermal response time. The use of a dynamic method to correct for the thermal inertia of the calorimeter is shown to reduce by one order of magnitude the time required to conduct a stepwise titration experiment involving a fast reaction. The ability to determine association constants of strong 1:1 complexes has been evaluated in terms of the precision of determining thermal energy.
Idioma:
Inglês
Tipo (Avaliação Docente):
Científica
Nº de páginas:
16
Documentos
Não foi encontrado nenhum documento associado à publicação.
A SYSTEM OF MICROCALORIMETERS (1994) Artigo em Revista Científica Internacional
BACKMAN, P; Bastos, M; BRIGGNER, LE; HAGG, S; HALLEN, D; LONNBRO, P; NILSSON, SO; OLOFSSON, G; SCHON, A; SUURKUUSK, J; TEIXEIRA, C; WADSO, I