Reactivity and Mechanistic Studies of the Reactions of Chlorodiphenylphosphine and Its Oxide with Methyl Glyoxylate, Glyoxylate Oximes, and Methyl Cyanoformate

• Tipo: Artigo em Revista Científica Internacional
• Data: 2015

Autores

Carlos A D Sousa (Autor) Outra; Carlos F R A C Lima (Autor) Outra; Ivo E Sampaio Dias (Autor) Outra; Xerardo Garcia Mera (Autor) Outra; Jose E Rodriguez Borges (Autor) FCUP

Revista

Título: Heteroatom Chemistry

Vol. 26

Páginas: 249-256

ISSN: 1042-7163

Editora: Wiley-Blackwell

Indexação

ISI Web of Knowledge - 5 Citações

Scopus - 5 Citações

Classificação Científica

FOS: Ciências exactas e naturais > Química

Outras Informações

ID Authenticus: P-00G-D8R

DOI: 10.1002/hc.21255

Abstract (EN): In this work, we describe the reactivity of chlorodiphenylphosphine and its oxide, as well as diphenylphosphine, with some glyoxylate derivative systems: methyl glyoxylate, methyl or 8-phenylneomenthyl glyoxylate oximes, and methyl cyanoformate. By analyzing the reactions outcomes and with the aid of computational chemistry, we propose some reaction mechanisms and molecular rearrangements.

Idioma: Inglês

Tipo (Avaliação Docente): Científica