Selective oxidative coupling of amines through light-activated bismuth halide perovskites

• Tipo: Artigo em Revista Científica Internacional
• Data: 2024

Autores

Lopes, JC (Autor) Outra; Albero, J (Autor) Outra; Sampaio, M.J. (Autor) FEUP; Claudia G Silva (Autor) FEUP; García, H (Autor) Outra; Joaquim Luís Faria (Autor) FEUP

Revista

Título: ChemCatChem

ISSN: 1867-3880

Editora: Wiley-Blackwell

Indexação

ISI Web of Knowledge - 0 Citações

Scopus - 0 Citações

Projetos Associados

LA LSRE-LCM - Financiamento Plurianual 2020-2023 para a Unidade LA LSRE-LCM Laboratório de Processos de Separação e Reacção - Laboratório de Catálise e Materiais

Outras Informações

ID Authenticus: P-00Z-XVR

DOI: 10.1002/cctc.202301432

Abstract (EN): Bismuth halide perovskites have emerged as promising alternatives for sustainable and efficient photocatalysts for light-induced organic transformations. Caesium bismuth halide perovskites (Cs3Bi2(ClxBr1-x)9) with different ratios of chloride and bromide were synthesised using a one-step solution process. These perovskites were then employed as photocatalysts for the photocatalytic oxidative coupling of benzylamine (BZA) to produce N-benzylidenebenzylamine (BZI) under ultraviolet-visible light radiation at ambient conditions. The incorporation of bromide ions into the chloride-based perovskite resulted in a noticeable reduction in the bandgap, leading to an enhancement in the photocatalytic activity. Conversely, the addition of chloride ions within the bromide-based perovskite was found to be beneficial for the material's photostability while simultaneously maintaining its high photocatalytic activity. The optimal compromise between the stability and photocatalytic activity for the BZI production was achieved using Cs3Bi2(Cl0.8Br0.2)9, being attained a total BZA conversion and the maximum BZI production with 100 % of selectivity after 6 hours of irradiation. The efficiency of this photocatalyst was ascribed to the highest current density observed during the photocurrent experiments, which improves the charge carrier mobility of the resulting material. Caesium bismuth halide perovskites with different ratios of chloride and bromide are synthesized through a one-step solution process. These perovskites demonstrated enhanced photocatalytic activity in the oxidative coupling of benzylamine toN-benzylidenebenzylamine under ultraviolet-visible light. Incorporating bromide ions improved photocatalytic efficiency, while adding chloride ions enhanced material photostability, achieving the best performance in Cs3Bi2(Cl0.8Br0.2)9. image

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 12