Improvement of DMFC Electrode Kinetics by using Nanohorns Catalyst Support

• Tipo: Artigo em Livro de Atas de Conferência Internacional
• Data: 2010

Autores

L. Brandão (Autor) FEUP; Daniele Mirabile Gattia (Autor) Outra; Renzo Marazzi (Autor) Outra; Marco Vittori-Antisari (Autor) Outra; Silvia Licoccia (Autor) Outra; Alessandra D’Epifanio (Autor) Outra; Enrico Traversa (Autor) Outra; A. Mendes (Autor) FEUP

Ata de Conferência Internacional

Título: THERMEC 2009, PTS 1-4

Páginas: 1106-1111

6th International Conference on Processing and Manufacturing of Advanced Materials

Berlin, GERMANY, AUG 25-29, 2009

Indexação

ISI Web of Knowledge - 8 Citações

ISI Web of Science

Scopus - 8 Citações

INSPEC

COMPENDEX

Classificação Científica

FOS: Ciências da engenharia e tecnologias > Outras ciências da engenharia e tecnologias

CORDIS: Ciências Físicas > Química

Outras Informações

ID Authenticus: P-003-D0X

DOI: 10.4028/www.scientific.net/msf.638-642.1106

Abstract (EN): One of the factors limiting direct methanol fuel cells (DMFC) performance is the slow kinetics of methanol oxidation at the anode The importance of the catalyst support for fuel cells has' been recognized and different forms of carbon have been suggested. Single wall nanohorns (SWNH) are a new class of carbon with a similar graphitic structure of carbon nanotubes. They are self-assembling materials that produce aggregates of about 100 nm In the present study, the comparison of the performance of a DMFC equipped with electrocatalysts supported on a commercial carbon black and on SWNH was carried out. The SWNH were synthesized by the arc discharge method in air. The deposition of the Pt and Pt/Ru catalysts on the carbon supports was accomplished by using ethylene glycol as reducing agent. The synthesized catalyst nanoparticles have a very small diameter size (ca. 2 5 nm) and they are uniformly distributed on both carbon supports. The supported electrode catalysts were tested in a DMFC and results indicate that employing SWNH is very promising showing catalytic activities 60 % higher.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Notas: Revista indexada no Journal Citation Reports.

Nº de páginas: 6