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Synthesis of regioisomeric functionalized benzodifurans and angelicins

Title
Synthesis of regioisomeric functionalized benzodifurans and angelicins
Type
Article in International Scientific Journal
Year
2009
Authors
Elias Quezada
(Author)
FCUP
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Delogu, G
(Author)
Other
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Vina, D
(Author)
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Santana, L
(Author)
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Podda, G
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Matos, MJ
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Picciau, C
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Journal
Vol. 92
Pages: 1309-1314
ISSN: 0018-019X
Publisher: Wiley-Blackwell
Indexing
Other information
Authenticus ID: P-007-QMS
Abstract (EN): Arenofurans have important biological and pharmacological activities. Compared to benzofurans, the reports on the synthesis of benzodifurans are rather limited. Here, we report the synthesis of a linear and an angular 3,3¿-bis(carboxymethyl)substituted benzodifuran and 4¿- carboxymethyl-substituted angelicins from phloroglucinol, using 4-halomethyl-substituted dipyrones as key intermediates in the synthetic route. This strategy shows that the stability of a pyrone ring depends on the type of substituent at C(4) and the conditions used. © 2009 Verlag Helvetica Chimica Acta AG.
Language: English
Type (Professor's evaluation): Scientific
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