Solution properties and solvatochromism of bis(N-2-pyridyl-salicylaldiminato)cobalt(II)

• Type: Article in International Scientific Journal
• Date: 2010

Authors

Krzysztof Kurzak (Author) Other; Iwona Kuzniarska Biernacka (Author) Other; Cristina Freire (Author) FCUP

Journal

Title: Structural Chemistry

Vol. 21 No. 2

Pages: 377-383

ISSN: 1040-0400

Publisher: Springer Nature

Indexing

ISI Web of Knowledge - 4 Citations

Scopus - 4 Citations

Scientific classification

FOS: Natural sciences > Chemical sciences

Other information

Authenticus ID: P-003-85G

DOI: 10.1007/s11224-009-9536-7

Abstract (EN): The bis(N-2-pyridyl-salicylaldiminato)cobalt(II) complex ([Co(sap)(2)]), a reddish-pink crystalline compound has been characterized by elemental analysis, molar conductivity, cyclic voltammetry, and Vis-NIR spectroscopy. Combination of all techniques indicates a tetrahedral geometry for the complex in solid state and in the solvents used. Electronic spectroscopy was used to determine the ligand-field parameters as well as chromaticity coordinates; for discrimination of color changes CIE and CIELAB color spaces have been applied.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 7