Synthesis and physical properties of 1-ethyl 3-methylpyridinium ethylsulfate and its binary mixtures with ethanol and water at several temperatures

• Type: Article in International Scientific Journal
• Date: 2008

Authors

Begoña González (Author) FEUP; Noelia Calvar (Author) FEUP; Elena Gómez (Author) Other; Eugénia A. Macedo (Author) FEUP; Ángeles Dominguez (Author) FEUP

Journal

Title: Journal of Chemical & Engineering Data

Vol. 53

Pages: 1824-1828

ISSN: 0021-9568

Publisher: American Chemical Society

Indexing

ISI Web of Knowledge - 41 Citations

ISI Web of Science

Scopus - 48 Citations

COMPENDEX

Scientific classification

FOS: Engineering and technology > Chemical engineering

CORDIS: Technological sciences

Other information

Authenticus ID: P-003-XBS

DOI: 10.1021/je800159w

Abstract (EN): In this paper, the ionic liquid [empy][EtSO4] Was synthesized, and its experimental densities, dynamic viscosities, and refractive indices were determined from (298.15 to 343.15) K. Densities and dynamic viscosities for [empy][EtSO4] + ethanol and + water at temperatures T = (298.15, 313.15, and 328.15) K have been measured over the whole composition range and at 0.1 MPa. The determined physical properties have never been reported. Excess molar volumes and viscosity deviations for the binary systems at the above-mentioned temperatures were calculated and fitted to the Redlich-Kister equation. Refractive indices were measured at 298.15 K over the whole composition range for ethanol (1) + [empy][EtSO4] (2) and water (1) + [empy][EtSO4] (2) binary systems. The results were used to calculate deviations in the refractive index.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 5