II - Material Balance
1. Fundamentals 1.1 The Different Types of Chemical Processes: Continuous, stepwise and semi-continuous processes; Processes in Stationary and Transition States. 1.2 The General Equation of Material Balance. 1.3 Methodology for the Calculation of Material Balance; Flow Diagrams. 1.4 The Different Types of Balance: Differential Balance and Comprehensive Balance. 1.5 Balance Involving Several Process Units; Recycling. 1.6 Balance in Reactive Processes; Degree of Conversion and Extent of Reaction; Competitive Reactions; Combustion Reactions.
2. Single Phase Systems 2.1 Condensed Phase Densities; Calculation and Methods of Estimation. Density Tables of Some Liquid Mixtures. 2.2 PVT Relationships in Gases and Ideal Mixtures. Standard Conditions. 2.3 PVT Relations in Real Gases; Virial coefficients; Cubic State Equations; Compressibility Factor; Law of Correspondent States.
3. Multiphase Systems. 3.1 Phase Diagrams of Pure Substances; Vapor Pressure of Pure Substances Equations. 3.2 Gas-Liquid Systems with a Condensable Component. Saturated Gas and Overheated Gas; Composition of a Saturated Gas-Steam System; Absolute and Relative Humidity; Materials Balance in a Condenser. 3.3 Phase Diagrams for Gas-Liquid Systems; Laws of Raoult and Henry. 3.4 Solid-Liquid Systems; Phase diagrams; Colligative Properties of Solutions. 3.5 Phase diagrams for liquid-liquid systems; Partially miscible and immiscible liquids; Distribution and Extraction Coefficient; Phase Diagrams for Ternary Systems.
III - Energy Balance1
Fundamentals 1.1 Forms of Energy. 1.2 Energy Balances in Closed Systems. 1.3 Energy Balances in Open Systems in Stationary State. 1.4 Thermodynamic properties of saturated steam and superheated steam; Tables and Diagrams of Vapor Pressure. 1.5 Methodology for the Calculation of Energy Balance. 1.6 Calculations on Simultaneous Energy and Material Balances.
2. Balances In Non-Reactive Processes. 2.1 State Properties and Pressure Variations; State Properties and Temperature Variations; Processes of Determination or Estimation of Heat Capacities. 2.2 Energy Balances in Single Phase Systems. 2.3 Operations Involving Phase Transitions; Determination or Estimation of Enthalpy of Vaporization and of Sublimation; Humidity diagrams. 2.4 Mixing and Solutions.
3. Energy Balance in Reactive Processes 3.1 Combustion and combustion reactions. Upper and lower calorific power. 3.2 Other reactive processes.
. ISBN: 0-471-53478-1
Hougen Olaf A. Olaf Andreas;
Practical note (40%) - The practical note (P) corresponds to the performance related to the presentation and discussion of problems as well as participation in class discussions
Theoretical component (60%)
The score of the theoretical component (T) is calculated as the mean obtained in the T1 and T2 evaluation tests or in the E1 and E2 parts of the exam, with the best of marks between T1 and E1 being counted and the best of marks between T2 and E2 .
T = 0.50x (E1 or T1) + 0.50x (E2 or T2)
Final grade = 0.40 x P + 0.60 x T
Conditions for approval in the discipline: T ≥ 8.5 and P ≥ 9.5 and Final grade ≥ 9.5
For final grades greater than 18 values it may be necessary to perform a complementary oral test
Students with an approved worker status, who can not attend the minimum number of classes, can solve a set of problems, and later presentation and discussion, to be proposed by the regent. The grade of this work (P) will represent the same percentage (40%) of the final grade. Alternatively, they may opt for 100% of the T grade.