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Thermodynamics of Industrial Processes

Code: Q3007     Acronym: Q3007     Level: 300

Keywords
Classification Keyword
OFICIAL Chemistry

Instance: 2018/2019 - 2S

Active? No
Responsible unit: Department of Chemistry and Biochemistry
Course/CS Responsible: Bachelor in Chemistry

Cycles of Study/Courses

Acronym No. of Students Study Plan Curricular Years Credits UCN Credits ECTS Contact hours Total Time
L:B 0 Official Study Plan 3 - 6 56 162
L:CC 0 Plano de estudos a partir de 2014 2 - 6 56 162
3
L:F 0 Official Study Plan 2 - 6 56 162
3
L:G 0 study plan from 2017/18 3 - 6 56 162
L:M 0 Official Study Plan 2 - 6 56 162
3
L:Q 0 study plan from 2016/17 3 - 6 56 162

Teaching language

Suitable for English-speaking students

Objectives

This discipline deals with topics of thermodynamics applied to various processes within the scope of industry and chemical engineering.

Learning outcomes and competences

Students are expected to be able to solve and solve problems typical of material and energy balances typical of several industrial processes, especially those related to Chemistry.

Working method

Presencial

Program

I - Basic Units and Variables in the Chemical Industry

1. Frequently Used Units in the Chemical Industry and their Conversion in SI Units.
2. Dimensional Groups and Dimensionally Homogeneous Equations.
3. Process Variables. 3.1 Flow Speeds: Units and Measurement - Different Types of Flowmeters; 3.2 Fluid Pressure: Units and Measurement - Different Types of Manometers; 3.3 Temperature: Units and Measurement - Different Types of Thermometers.



II - Material Balance

1. Fundamentals 1.1 The Different Types of Chemical Processes: Continuous, stepwise and semi-continuous processes; Processes in Stationary and Transition States. 1.2 The General Equation of Material Balance. 1.3 Methodology for the Calculation of Material Balance; Flow Diagrams. 1.4 The Different Types of Balance: Differential Balance and Comprehensive Balance. 1.5 Balance Involving Several Process Units; Recycling. 1.6 Balance in Reactive Processes; Degree of Conversion and Extent of Reaction; Competitive Reactions; Combustion Reactions.
2. Single Phase Systems 2.1 Condensed Phase Densities; Calculation and Methods of Estimation. Density Tables of Some Liquid Mixtures. 2.2 PVT Relationships in Gases and Ideal Mixtures. Standard Conditions. 2.3 PVT Relations in Real Gases; Virial coefficients; Cubic State Equations; Compressibility Factor; Law of Correspondent States.
3. Multiphase Systems. 3.1 Phase Diagrams of Pure Substances; Vapor Pressure of Pure Substances Equations. 3.2 Gas-Liquid Systems with a Condensable Component. Saturated Gas and Overheated Gas; Composition of a Saturated Gas-Steam System; Absolute and Relative Humidity; Materials Balance in a Condenser. 3.3 Phase Diagrams for Gas-Liquid Systems; Laws of Raoult and Henry. 3.4 Solid-Liquid Systems; Phase diagrams; Colligative Properties of Solutions. 3.5 Phase diagrams for liquid-liquid systems; Partially miscible and immiscible liquids; Distribution and Extraction Coefficient; Phase Diagrams for Ternary Systems.

III - Energy Balance1
Fundamentals 1.1 Forms of Energy. 1.2 Energy Balances in Closed Systems. 1.3 Energy Balances in Open Systems in Stationary State. 1.4 Thermodynamic properties of saturated steam and superheated steam; Tables and Diagrams of Vapor Pressure. 1.5 Methodology for the Calculation of Energy Balance. 1.6 Calculations on Simultaneous Energy and Material Balances.
2. Balances In Non-Reactive Processes. 2.1 State Properties and Pressure Variations; State Properties and Temperature Variations; Processes of Determination or Estimation of Heat Capacities. 2.2 Energy Balances in Single Phase Systems. 2.3 Operations Involving Phase Transitions; Determination or Estimation of Enthalpy of Vaporization and of Sublimation; Humidity diagrams. 2.4 Mixing and Solutions.
3. Energy Balance in Reactive Processes 3.1 Combustion and combustion reactions. Upper and lower calorific power. 3.2 Other reactive processes.


 

Mandatory literature

Felder Richard M.; Elementary principles of chemical processes. ISBN: 0-471-53478-1

Complementary Bibliography

Hougen Olaf A. Olaf Andreas; Chemical process principles

Teaching methods and learning activities

theoretical-practical classes

Evaluation Type

Distributed evaluation with final exam

Assessment Components

designation Weight (%)
Exame 60,00
Participação presencial 40,00
Total: 100,00

Amount of time allocated to each course unit

designation Time (hours)
Frequência das aulas 56,00
Total: 56,00

Eligibility for exams

Class attendance is compulsory. It loses the frequency those who miss more than 1/4 of the classes planned.

Calculation formula of final grade

Practical note (40%) - The practical note (P) corresponds to the performance related to the presentation and discussion of problems as well as participation in class discussions

Theoretical component (60%)
The score of the theoretical component (T) is calculated as the mean obtained in the T1 and T2 evaluation tests or in the E1 and E2 parts of the exam, with the best of marks between T1 and E1 being counted and the best of marks between T2 and E2 .

T = 0.50x (E1 or T1) + 0.50x (E2 or T2)

Final grade = 0.40 x P + 0.60 x T

Conditions for approval in the discipline: T ≥ 8.5 and P ≥ 9.5 and Final grade ≥ 9.5
For final grades greater than 18 values ​​it may be necessary to perform a complementary oral test

Students with an approved worker status, who can not attend the minimum number of classes, can solve a set of problems, and later presentation and discussion, to be proposed by the regent. The grade of this work (P) will represent the same percentage (40%) of the final grade. Alternatively, they may opt for 100% of the T grade.
 

 

Special assessment (TE, DA, ...)

Students with special status who disregard them from class attendance can do written work on a topic proposed by the teacher as an alternative to attendance and participation in the classes (40% of the final grade)

Classification improvement

Exam-second period

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