Inorganic Chemistry
Keywords |
Classification |
Keyword |
OFICIAL |
Chemistry |
Instance: 2018/2019 - 1S 
Cycles of Study/Courses
Teaching language
Suitable for English-speaking students
Objectives
Deepen the knowledge on coordination chemistry: electronic properties, magnetic and chemical reactions of ctransition metal ion compounds.
Recognize the applications of several inorganic compounds: Catalysis, Materials Chemistry and Nanoquimics and Biological Chemistry.
Learning outcomes and competences
Deepen the knowledge on the Chemistry of Coordination CompoundsKnow how to identify isomers. To know the chemical bonding models of the coordination compounds: Crystal field theory and ligand field. Understand the reactions in metallic complexes: equilibrium of complexation. Effects of stereochemical nature. Change to spin state. Effect of Jahn-Teller. Irving-Williams Series. Inert-labile character. Chelate effect, macrocyclic effect.
Understanding electronic spectroscopy in metal complexes
Know how to identify the free ion terms and use the Tanabe-Sugano diagrams. Interoperating the electronic spectra: electronic transitions: rules of selection and intensity of the bands
Know the basic concepts of Magnetismapplied to ccomplexes.
Know the basics of Organometallic ChemistryUnderstand the chemical bond in organometallic complexes: rule of the 18 electrons. Know how to characterize the type of organometallic compounds
Know the basics of Solid State Chemistry and Materials ChemistryKnow how to prepare bulk materials, understand defects and ionic transport.
Know how to give examples of materials and know their applications: Oxides, nitrides and metal fluorides. Calcogenides, intercalation compounds and metal rich phases. Structures with network organization. Hydrides and materials for hydrogen storage. Inorganic pigments. Chemistry of semiconductors. Molecular materials and fullerene anions.
Understand the concepts of Nano Chemistry through its basic principles: Nanosciences and Nanotechnologies.
Know the basic principles associated with homogeneous catalysis and heterogeneous catalysis.
Understand the basic principles associated with Inorganic Biological Chemistry
Working method
Presencial
Program
">1. Chemistry of Coordination Compounds
">1.1 Chemistry of Coordination Compounds general concepts.
1.2. ">Isomeria, Isomers: compounds composed of similar atoms, but exhibiting a different spatial distribution and / or different type of binding.
1.3. ">Chemical Bonding Models: Crystal Field Theory, Ligangando Field Theory.
1.4. Reactions in metallic complexes: Complexation equilibrium. Effects of stereochemical nature. Change to spin state. Effect of Jahn-Teller. Irving-Williams Series. Inert-labile character. ">Chelate effect, macrocyclic effect.
">2. Electron spectroscopy in metal complexes
">2.1 Terms of the free ion
">2.2 Tanabe-Sugano diagrams.
">2.3 Electronic spectra: electronic transitions: rules of selection and intensity of bands
">2.4 Magnetism.
">2.5 Luminescence: technological application
">3. Organometallic Chemistry
">3.1 Chemical bonding in organometallic complexes: rule of 18 electrons.
">3.2 Type of organometallic compounds
">4. Solid State and Chemical Materials
">4.1 Preparation of Bulk Materials
">4.2 Defects and ionic transport
4.3 Examples of materials and their applications: Metal oxides, nitrides and fluorides.Calcogenides, intercalation compounds and metal rich phases. Strucures with network organization. Hydrides and materials for hydrogen storage. Inorganic pigments.Chemistry of semiconductors. ">Molecular materials and fullerene anions.
4.4 Introduction to the concepts of Nanochemistry. Basic principles: Nanosciences and Nanotechnologies. Bulk materials vs nanomaterials. Methods of preparation for denaturances. ">Non-molecular self-assembly.
">5. Catalysis
">5.1 General principles.
">5.2 Homogeneous catalysis
">5.3 Heterogeneous catalysis
">6. Inorganic Biological Chemistry
">6.1 Transport of metal ions .
">6.2 Catalytic processes.
6.3 Metals in the regulation of genes.
Mandatory literature
Weller,M., Rourke, J., Overton, T., Armstrong, F.; Inorganic Chemistry, 7th Edition, OUP
Atkins Peter William 1940- 070;
Shriver & Atkins inorganic chemistry. ISBN: 978-0-19-926463-6
Complementary Bibliography
Catherine E. Housecroft, Alan G. Sharpe;; Inorganic Chemistry, 4th edition, Pearson
Teaching methods and learning activities
Theoretical Lectures:
The slides presented in the classes will be available on the course page. Internet sites and files will be available to complement the UC study. The UP Moodle platform will be used in the management of UC.
Theoretical-practical classes:
Solving problems related to the subject taught in theoretical classes. Students will form groups of 3 and / or 2 students. Groups will have to prepare problem solving at home to be presented during TP classes.
An intermediate test will be held during the month of November
keywords
Physical sciences > Chemistry > Inorganic chemistry
Physical sciences > Chemistry > Molecular chemistry
Physical sciences > Chemistry > Homogeneous catalysis
Technological sciences > Technology > Nanotechonology
Physical sciences > Chemistry > Structural chemistry
Physical sciences > Chemistry > Heterogeneous catalysis
Evaluation Type
Distributed evaluation with final exam
Assessment Components
designation |
Weight (%) |
Exame |
70,00 |
Participação presencial |
30,00 |
Total: |
100,00 |
Amount of time allocated to each course unit
designation |
Time (hours) |
Estudo autónomo |
106,00 |
Frequência das aulas |
56,00 |
Total: |
162,00 |
Eligibility for exams
Students can not miss more than 1/4 of the scheduled classes - 14. Thus, they can not have more than 4 absences to the classes TPs
The final grade of the TP classes must be equal to or greater than 9.5 points.
Calculation formula of final grade
FINAL MARK= (0.70 x Exam) + (0.30 x TP classes)In all assessments rounding to tenths is considered
EVALUATION EXAMINATION:
1 - Intermediate test + final exam (normal periode): The intermediate test will be done during the month of November.
If the student has a mark of 7.0 or higher, he may be excused from taking the final exam on the normal evaluation period, of the part of the subject matter of the intermediate test. In this case, the examination will be on the matter not covered by the intermediate test. The grade of the exam cannot be less than 7.0 values.
The final evaluation will be: (intermediate grade + exam grade on the normal evaluation) / 2 In none of the evaluations the grade may be less than 7,0 values.
If the student obtains in the normal evaluation period a grade inferior to 7.0 values, he will have to carry out a new evaluation in the time of appeal. In this case, he will have to make the evaluation on all the subject taught, leaving the intermediate test score without any effect on the final classification.
EVALUATION EXAMINATION:
2 - Final exam (normal or appeal period): If the student has a score lower than 7 in the intermediate test he will have to take the final exam in the normal evaluation period or in the appeal period on all the subject taught. The intermediate test grade will have no effect on the final classification. For the student to get approved the examination grade on normal evaluation period or appeal period must be equal to or higher than 7.0 values.
Assessment THEORETICAL-PRACTICAL CLASSES: 30% of the final grade of the UC: minimum grade of 9.5 values.
Special assessment (TE, DA, ...)
Worker Students:
With attendance to TP classes = ordinary students. The final grade is calculated in the same way as ordinary students
Without attendance to TP classes : final exam or intermediate test + final exam. In this case the final marck of the UC corresponds to the exam grade or intermediate test + exam
Classification improvement
Final exam.